A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

被引：34

作者：

Coe, BJ

Harris, JA

Clays, K

Persoons, A

Wostyn, K

Brunschwig, BS

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Louvain, Dept Chem, B-3001 Louvain, Belgium

[3] Univ Arizona, Ctr Opt Sci, Tucson, AZ 85721 USA

[4] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b103543f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities beta (0) than [5-8]PF6, because the higher HOMO energy of a {Ru-II(NH3)(5)}(2+) centre more than offsets the superior pi -orbital overlap in the purely organic chromophores.

引用

收藏

页码：1548 / 1549

页数：2

相关论文

共 20 条

[1] Stark spectroscopy: Applications in chemistry, biology, and materials science [J].

Bublitz, GU ;

Boxer, SG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1997, 48 :213-242

[2] Tuning of charge-transfer absorption and molecular quadratic non-linear optical properties in ruthenium(II) ammine complexes [J].

Coe, BJ ;

Harris, JA ;

Asselberghs, I ;

Persoons, A ;

Jeffery, JC ;

Rees, LH ;

Gelbrich, T ;

Hursthouse, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (20) :3617-3625

[3]

Coe BJ, 1999, CHEM-EUR J, V5, P2464, DOI 10.1002/(SICI)1521-3765(19990903)5:9<2464::AID-CHEM2464>3.0.CO

[4]

2-L

[5]

Coe BJ, 1999, ANGEW CHEM INT EDIT, V38, P366, DOI 10.1002/(SICI)1521-3773(19990201)38:3<366::AID-ANIE366>3.0.CO

[6]

2-D

[7] Large molecular quadratic hyperpolarizabilities in donor/acceptor-substituted trans-tetraammineruthenium(II) complexes [J].

Coe, BJ ;

Chamberlain, MC ;

EssexLopresti, JP ;

Gaines, S ;

Jeffery, JC ;

Houbrechts, S ;

Persoons, A .

INORGANIC CHEMISTRY, 1997, 36 (15) :3284-3292

[8] Enhancement of molecular quadratic hyperpolarizabilities in ruthenium(II) 4,4′-bipyridinium complexes by N-phenylation [J].

Coe, BJ ;

Harris, JA ;

Harrington, LJ ;

Jeffery, JC ;

Rees, LH ;

Houbrechts, S ;

Persoons, A .

INORGANIC CHEMISTRY, 1998, 37 (13) :3391-3399

[9] Hyper-Rayleigh Scattering in isotropic solution [J].

Hendrickx, E ;

Clays, K ;

Persoons, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (10) :675-683

[10] STRUCTURE-COLOR RELATIONSHIPS OF SOME NEW N-ARYLPYRIDINIUM HEMICYANINE DYES [J].

HUTCHINGS, MG .

TETRAHEDRON, 1984, 40 (11) :2061-2068