A Convenient Synthesis and a NMR Study of the Diammoniate of Diborane

被引：21
作者：
Lingam, Hima K. [1 ]
Chen, Xuenian [1 ,2 ]
Zhao, Ji-Cheng [2 ]
Shore, Sheldon G. [1 ]
机构：
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
[2] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 12期
关键词：
boron; diammoniate of diborane; hydrogen storage; metathesis; NMR spectroscopy; CHEMICAL EVIDENCE; AMMONIA-BORANE; HYDROGEN STORAGE; LIQUID AMMONIA; BOROHYDRIDE; METAL; CHEMISTRY; HYDRIDES; SODIUM; H3NBH3;
D O I：
10.1002/chem.201103693
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
DADB synthesis: The diammoniate of diborane (DADB) was synthesized in a new metathesis reaction between the diammoniate of monochloroborane and potassium borohydride in liquid ammonia (see scheme). 1H and 11B NMR spectra of DADB are reported. The stability in THF was examined by variable-temperature 11B NMR spectroscopy. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：3490 / 3492
页数：3
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