Magnet-responsive, superhydrophobic fabrics from waterborne, fluoride-free coatings

被引:33
作者
Fu, Sida [1 ]
Zhou, Hua [1 ]
Wang, Hongxia [1 ]
Ding, Jie [2 ]
Liu, Shuai [3 ]
Zhao, Yan [1 ]
Niu, Haitao [1 ]
Rutledge, Gregory C. [4 ]
Lin, Tong [1 ]
机构
[1] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
[2] Def Sci & Technol Grp, Fishermans Bend, Vic 3207, Australia
[3] Soochow Univ, Sch Mat & Elect Engn, Suzhou 215000, Peoples R China
[4] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
基金
澳大利亚研究理事会;
关键词
OIL-ABSORPTION; SEPARATION; MEMBRANE; ROBUST; RESISTANT; OXIDATION; PROPERTY; SURFACES; SPONGES;
D O I
10.1039/c7ra10941e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, durable superhydrophobic fabrics with magnet responsive properties were prepared by a two-step coating technique using polydopamine (PDA), Fe3O4 nanoparticles, and hexadecyltrimethoxysilane as coating materials. The coated fabrics exhibit fast magnetic responsivity and a water contact angle of 156 degrees. The coating is durable enough to withstand at least 50 cycles of home laundering and 500 cycles of Martindale abrasions without losing its superhydrophobicity and magnetic properties. The PDA pre-coating plays a significant role in improving the adhesion of hydrophobic Fe3O4 nanoparticles on fabric surface. The coated fabric is highly oleophilic (oil contact angle = 0 degrees). When used for absorbing oil, the coated fabric floats naturally on the surface of oily water, and it can be moved to approach oil drops under magnetic actuation. The fabric is reusable for at least 10 cycles. This may offer an environmentally friendly way to prepare "smart" oil-recovery materials.
引用
收藏
页码:717 / 723
页数:7
相关论文
共 38 条
[1]   Natural and biomimetic artificial surfaces for superhydrophobicity, self-cleaning, low adhesion, and drag reduction [J].
Bhushan, Bharat ;
Jung, Yong Chae .
PROGRESS IN MATERIALS SCIENCE, 2011, 56 (01) :1-108
[2]   Cross-linking in adhesive quinoproteins: Studies with model decapeptides [J].
Burzio, LA ;
Waite, JH .
BIOCHEMISTRY, 2000, 39 (36) :11147-11153
[3]   Robust fluorine-free superhydrophobic PDMS-ormosil@fabrics for highly effective self-cleaning and efficient oil-water separation [J].
Cao, Chunyan ;
Ge, Mingzheng ;
Huang, Jianying ;
Li, Shuhui ;
Deng, Shu ;
Zhang, Songnan ;
Chen, Zhong ;
Zhang, Keqin ;
Al-Deyab, Salem S. ;
Lai, Yuekun .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (31) :12179-12187
[4]   Anti-Icing Superhydrophobic Coatings [J].
Cao, Liangliang ;
Jones, Andrew K. ;
Sikka, Vinod K. ;
Wu, Jianzhong ;
Gao, Di .
LANGMUIR, 2009, 25 (21) :12444-12448
[5]   Polyurethane sponge functionalized with superhydrophobic nanodiamond particles for efficient oil/water separation [J].
Cao, Ning ;
Yang, Bai ;
Barras, Alexandre ;
Szunerits, Sabine ;
Boukherroub, Rabah .
CHEMICAL ENGINEERING JOURNAL, 2017, 307 :319-325
[6]   A general method for the incorporation of nanoparticles into superhydrophobic films by aerosol assisted chemical vapour deposition [J].
Crick, Colin R. ;
Bear, Joseph C. ;
Southern, Paul ;
Parkin, Ivan P. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (13) :4336-4344
[7]   Super-stable non-woven fabric-based membrane as a high-efficiency oil/water separator in full pH range [J].
Diao, Zhongwei ;
Wang, Lei ;
Yu, Peng ;
Feng, He ;
Zhao, Li ;
Zhou, Wei ;
Fu, Honggang .
RSC ADVANCES, 2017, 7 (32) :19764-19770
[8]   Magnet-Induced Temporary Superhydrophobic Coatings from One-Pot Synthesized Hydrophobic Magnetic Nanoparticles [J].
Fang, Jian ;
Wang, Hongxia ;
Xue, Yuhua ;
Wang, Xungai ;
Lin, Tong .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (05) :1449-1455
[9]   Wetting and self-cleaning properties of artificial superhydrophobic surfaces [J].
Fürstner, R ;
Barthlott, W ;
Neinhuis, C ;
Walzel, P .
LANGMUIR, 2005, 21 (03) :956-961
[10]  
Giesy J. P., 2002, JOURNAL, P147