Energy transfer and thermal stability of K2Ba(WO4)2: Eu3+,Sm3+ phosphors

被引：31

作者：

Chen, Junhua ^{[1
]}

Zhao, Weiren ^{[1
]}

Wang, Jianqing ^{[1
]}

Wang, Nenghuo ^{[1
]}

Meng, Yingjun ^{[1
]}

He, Jun ^{[2
]}

Zhang, Xin ^{[3
]}

机构：

[1] Guangdong Univ Technol, Sch Phys & Optoelect Engn, Guangzhou 510006, Guangdong, Peoples R China

[2] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China

[3] Guangdong Univ Technol, Art Design Coll, Guangzhou 510006, Guangdong, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2015年 / 41卷 / 09期

关键词：

Luminescence; Energy transfer; Sm3+-Eu3+; Thermal stability; LANTHANIDE AQUO IONS; LUMINESCENCE PROPERTIES; PHOTOLUMINESCENCE; SM3+; SYSTEM; STATE;

D O I：

10.1016/j.ceramint.2015.06.006

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Novel red-emitting K2Ba(WO4)(2): Eu3+, Sm3+ phosphors were synthesized by the solid-state reaction method. The phase formation, morphology, luminescent properties, energy transfer, concentration quenching and thermal quenching behavior were investigated. The PL intensities of the phosphors were enhanced by the addition of Sm3+ due to the energy transfer from Sm3+ to Eu3+. The analyses of PL decay curves confirmed the energy transfer from Sm3+ to Eu3+. The mechanism of energy transfer was proved to be the dipole dipole interaction. The thermal quenching temperature of KBW: Eu3+, Sm3+ was above 463 K, indicating this phosphor had a good thermal stability. The results indicated that KBW: Eu3+, Sm3+ phosphor is a candidate of the red phosphor for w-LEDs. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

引用

页码：11945 / 11952

页数：8

共 40 条

[1] An investigation on photoluminescence and energy transfer of Eu3+/Sm3+ single-doped and co-doped Ca4YO(BO3)3 phosphors [J].

Bandi, Vengala Rao ;

Grandhe, Bhaskar Kumar ;

Jang, Kiwan ;

Shin, Dong-Soo ;

Yi, Soung-Soo ;

Jeong, Jung-Hyun .

MATERIALS CHEMISTRY AND PHYSICS, 2013, 140 (2-3) :453-457

[2] Energy transfer in Sm3+:Eu3+ system in zinc sodium phosphate glasses [J].

Biju, PR ;

Jose, G ;

Thomas, V ;

Nampoori, VPN ;

Unnikrishnan, NV .

OPTICAL MATERIALS, 2004, 24 (04) :671-677

[3] ENERGY TRANSFER IN OXIDIC PHOSPHORS [J].

BLASSE, G .

PHYSICS LETTERS A, 1968, A 28 (06) :444-&

[4]

Blasse G., 1994, LUMINESCENT MAT, P1, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1, 10.1007/978-3-642-79017-11, DOI 10.1007/978-3-642-79017-11]

[5] ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&

[6] ELECTRONIC ENERGY LEVELS OF TRIVALENT LANTHANIDE AQUO IONS .4. EU3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4450-&

[7] Synthesis, EXAFS investigation and optical spectroscopy of nanocrystalline Gd3Ga5O12 doped with Ln3+ ions (Ln = Eu, Pr) [J].

Daldosso, Matteo ;

Falcomer, Daniele ;

Speghini, Adolfo ;

Ghigna, Paolo ;

Bettinelli, Marco .

OPTICAL MATERIALS, 2008, 30 (07) :1162-1167

[8] THEORY OF CONCENTRATION QUENCHING IN INORGANIC PHOSPHORS [J].

DEXTER, DL ;

SCHULMAN, JH .

JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (06) :1063-1070

[9]

Fang Y.-C., 2011, J ELECTROCHEM SOC J, VJ1, P158

[10] EU+3 5D RESONANCE QUENCHING TO CHARGE-TRANSFER STATES IN Y2O2S,LA2O2S, AND LAOCL [J].

FONGER, WH ;

STRUCK, CW .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (12) :6364-&

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