Solar Photochemical Synthesis: From the Beginnings of Organic Photochemistry to the Solar Manufacturing of Commodity Chemicals

被引:208
作者
Oelgemoller, Michael [1 ]
机构
[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia
关键词
LIGHT PHOTOREDOX CATALYSIS; FRIEDEL-CRAFTS ACYLATION; RESEARCH-AND-DEVELOPMENT; GREEN PHOTOCHEMISTRY; FINE CHEMICALS; ENERGY-EFFICIENT; SUSTAINABLE CHEMISTRY; EPSILON-CAPROLACTAM; ECONOMIC-EVALUATION; EMITTING-DIODES;
D O I
10.1021/acs.chemrev.5b00720
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Natural sunlight Offers:a cost-efficient and sustainable energy source for photochemical reactions. In contrast to the lengthy and small-scale "flask in the sun" procedures of the past, modem solar Concentrator systems nowadays significantly shorten reaction times and enable technical-scale operations. After a brief historical introduction, this review presents the Most important solar reactor types and their successful application in preparative solar syntheses. The examples demonstrate, that solar manufacturing of fine chemicals, is technically feasible and environmentally sustainable. After over 100 years, 'Ciamician's prophetic:Vision of "the photochemistry' of the future" as a clean and green Manufacturing methodology has yet to be realized. At the same time, his warning, "for nature is not in a hurry but mankind is" is still valid today It is hoped that this review will lead to a renewed interest in this truly enlightening technology, that it will stimulate photochemists and photochemical engineers to "go back to the roots onto the roofs" and that it will ultimately result in industrial applications in the foreseeable future.
引用
收藏
页码:9664 / 9682
页数:19
相关论文
共 190 条
[121]   An overview of hydrogen gas production from solar energy [J].
Ngoh, Simon Koumi ;
Njomo, Donatien .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (09) :6782-6792
[122]   Isolation, characterization and evaluation of photochemical potential of rice husk-based furfural via continuous flow reactor [J].
Nsubuga, Hakimu ;
Basheer, Chanbasha ;
Al-Muallem, Hasan Ali Saleh ;
Kalanthoden, Abdul Nasar .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2016, 4 (01) :857-863
[123]   Enhancing fine chemicals process chemistry - A practical approach [J].
Obenndip, DA ;
Sharratt, PN .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2005, 83 (A6) :655-661
[124]   A solar-driven, complex catalyzed pyridine synthesis as alternative for a thermally-driven synthesis [J].
Oehme, G ;
Heller, B ;
Wagler, P .
ENERGY, 1997, 22 (2-3) :327-336
[125]   Green photochemistry:: Production of fine chemicals with sunlight [J].
Oelgemoeller, Michael ;
Jung, Christian ;
Mattay, Jochen .
PURE AND APPLIED CHEMISTRY, 2007, 79 (11) :1939-1947
[126]   Green photochemistry:: solar-chemical synthesis of Juglone with medium concentrated sunlight [J].
Oelgemoeller, Michael ;
Healy, Niall ;
de Oliveira, Lamark ;
Jung, Christian ;
Mattay, Jochen .
GREEN CHEMISTRY, 2006, 8 (09) :831-834
[127]   The Applied and Green Photochemistry research group at James Cook University in Townsville, Australia [J].
Oelgemoeller, Michael ;
Bolte, Matthew .
GREEN PROCESSING AND SYNTHESIS, 2014, 3 (02) :163-165
[128]   Green Photochemical Processes and Technologies for Research & Development, Scale-up and Chemical Production [J].
Oelgemoeller, Michael .
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2014, 61 (07) :743-748
[129]   Highlights of Photochemical Reactions in Microflow Reactors [J].
Oelgemoeller, Michael .
CHEMICAL ENGINEERING & TECHNOLOGY, 2012, 35 (07) :1144-1152
[130]   Recent Advances in Microflow Photochemistry [J].
Oelgemoeller, Michael ;
Shvydkiv, Oksana .
MOLECULES, 2011, 16 (09) :7522-7550