Model-based analysis for the thermal management of open-cathode proton exchange membrane fuel cell systems concerning efficiency and stability

被引:37
作者
Strahl, Stephan [1 ]
Costa-Castello, Ramon [2 ]
机构
[1] CSIC UPC, Inst Robot & Informat Ind, Parc Tecnol Barcelona,C Llorens & Artigas 4-6, Barcelona 08028, Spain
[2] Univ Politecn Cataluna, U Bldg FME,507,C Pau Gargallo 5, E-08028 Barcelona, Catalunya, Spain
关键词
Open-cathode PEM fuel cell; Modeling; Stability analysis; Efficiency improvement; TEMPERATURE-RANGE; CATALYST LAYERS; PERFORMANCE;
D O I
10.1016/j.jprocont.2016.09.004
中图分类号
TP [自动化技术、计算机技术];
学科分类号
0812 ;
摘要
In this work we present a dynamic, control-oriented, concentrated parameter model of an open-cathode proton exchange membrane fuel cell system for the study of stability and efficiency improvement with respect to thermal management. The system model consists of two dynamic states which are the fuel cell temperature and the liquid water saturation in the cathode catalyst layer. The control action of the system is the inlet air velocity of the cathode air flow manifold, set by the cooling fan, and the system output is the stack voltage. From the model we derive the equilibrium points and eigenvalues within a set of operating conditions and subsequently discuss stability and the possibility of efficiency improvement. The model confirms the existence of a temperature-dependent maximum power in the moderate temperature region. The stability analysis shows that the maximum power line decomposes the phase plane in two parts, namely stable and unstable equilibrium points. The model is capable of predicting the temperature of a stable steady-state voltage maximum and the simulation results serve for the design of optimal thermal management strategies. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:201 / 212
页数:12
相关论文
共 18 条
[1]  
Barbir F, 2005, SUSTAIN WORLD SER, P1
[2]   Two-phase flow and maldistribution in gas channels of a polymer electrolyte fuel cell [J].
Basu, Suman ;
Li, Jun ;
Wang, Chao-Yang .
JOURNAL OF POWER SOURCES, 2009, 187 (02) :431-443
[4]   A single-phase, non-isothermal model for PEM fuel cells [J].
Ju, H ;
Meng, H ;
Wang, CY .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2005, 48 (07) :1303-1315
[5]  
Khalil H., 2014, Control of Nonlinear Systems
[6]   Water sorption, desorption and transport in Nafion membranes [J].
Majsztrik, Paul W. ;
Satterfield, M. Barclay ;
Bocarsly, Andrew B. ;
Benziger, Jay B. .
JOURNAL OF MEMBRANE SCIENCE, 2007, 301 (1-2) :93-106
[7]   Liquid water transport in gas diffusion layer of polymer electrolyte fuel cells [J].
Pasaogullari, U ;
Wang, CY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (03) :A399-A406
[8]  
Pukrushpan J.T., 2004, ADV IND CON
[9]  
Slotine J., 1991, APPL NONLINEAR CONTR
[10]   PEM fuel cell reaction kinetics in the temperature range of 23-120°C [J].
Song, Chaojie ;
Tang, Yanghua ;
Zhang, Jian Lu ;
Zhang, Jiujun ;
Wang, Haijiang ;
Shen, Jun ;
McDermid, Scott ;
Li, Jing ;
Kozak, Paul .
ELECTROCHIMICA ACTA, 2007, 52 (07) :2552-2561