The most hindered hydrotris(pyrazolyl)borate ligand, X-ray structure of chlorocopper(II) complex:: [Cu(Cl){HB(3-Ad-5-Pripz)3}] as compared with [Cu(Cl){HB(3-But-5-Pripz)3}]

被引：30

作者：

Fujisawa, K ^{[1
]}

Tada, N

Ishikawa, Y

Higashimura, H

Miyashita, Y

Okamoto, KI

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

[2] Sumitomo Chem Co Ltd, Tsukuba Res Lab, Tsukuba, Ibaraki 3003294, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 02期

基金：

日本学术振兴会;

关键词：

copper(II); hydrotris(pyrazolyl)borate; mononuclear complex; crystal structure;

D O I：

10.1016/j.inoche.2003.10.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Admantyl substituted hydrotris(pyrazolyl)borate ligand, which is the most hindered in all the hydrotris(pyrazolyl)borate ligands, is newly synthesized. Two chlorocopper(II) complexes with [HB(3-Ad-5-Pr(i)pz)(3)](-) and [HB(3-Bu-t-5-Pr(i)PZ)(3)](-) were characterized by X-ray diffraction and some spectroscopic techniques. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：209 / 212

页数：4

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