Catalytic functionalization of arenes and alkanes via C-H bond activation

被引：1331

作者：

Jia, CG ^{[1
]}

Kitamura, T ^{[1
]}

Fujiwara, Y ^{[1
]}

机构：

[1] Kyushu Univ, Fac Engn, Dept Appl Chem, Fukuoka 8128581, Japan

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2001年 / 34卷 / 08期

关键词：

D O I：

10.1021/ar000209h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several novel synthetic reactions of arenes and alkanes discovered and investigated in our laboratory are summarized here. These include olefin arylation, hydroarylation of alkynes, hydroxylation of arenes, carboxylation of arenes. and alkanes, and aminomethylation and acetoxylation of alkanes. Most of these reactions are catalyzed by highly electrophilic transition metal cationic species generated in situ in an acid medium, involving electrophilic metalation of C-H bonds of arenes and alkanes which lead to the formation of aryl-metal and alkyl-metal sigma -complexes.

引用

页码：633 / 639

页数：7

共 82 条

[1]

Asadullah M, 1998, APPL ORGANOMET CHEM, V12, P277

[2]

Asadullah M, 2000, ANGEW CHEM INT EDIT, V39, P2475, DOI 10.1002/1521-3773(20000717)39:14<2475::AID-ANIE2475>3.0.CO

[3]

2-Y

[4] AROMATIC SUBSTITUTION OF OLEFINS .20. REACTIONS OF TRIPHENYLAMINE, TRI-PHOSPHINE, TRI-ARSINE, TRI-STIBINE, AND TRI-BISMUTH WITH STYRENE IN PRESENCE OF PALLADIUM (II) SALTS [J].

ASANO, R ;

MORITANI, I ;

FUJIWARA, Y ;

TERANISH.S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (09) :2910-2911

[5] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[6] Metal-alkyl bond protonolysis studies of (dfepe)Pt(Me)X complexes in acidic media [J].

Bennett, BL ;

Hoerter, JM ;

Houlis, JF ;

Roddick, DM .

ORGANOMETALLICS, 2000, 19 (04) :615-621

[7] INSERTION OF ACETYLENES INTO CARBON HYDROGEN-BONDS CATALYZED BY RHODIUM TRIMETHYLPHOSPHINE COMPLEXES [J].

BOESE, WT ;

GOLDMAN, AS .

ORGANOMETALLICS, 1991, 10 (03) :782-786

[8] INTERMOLECULAR ACTIVATION OF C-D BONDS IN BENZENE-D6 BY TRANS-NEOPENTYL(TRIFLUOROMETHANESULFONATO)BIS(TRIMETHYL-PHOSPHINE)PLATINUM(II) [J].

BRAINARD, RL ;

NUTT, WR ;

LEE, TR ;

WHITESIDES, GM .

ORGANOMETALLICS, 1988, 7 (11) :2379-2386

[9] Palladium-catalysed hydroarylation and hydrovinylation of 3,3-dialkoxy-1-aryl-1-propynes. An approach to 3-aryl- and 3-vinylquinolines [J].

Cacchi, S ;

Fabrizi, G ;

Marinelli, F ;

Moro, L ;

Pace, P .

TETRAHEDRON, 1996, 52 (30) :10225-10240

[10] Thermal, catalytic, regiospecific functionalization of alkanes [J].

Chen, HY ;

Schlecht, S ;

Semple, TC ;

Hartwig, JF .

SCIENCE, 2000, 287 (5460) :1995-1997

← 1 2 3 4 5 6 7 8 9 →