Fabrication of lignin-based biochar containing multi-metal ferrite and efficient removal for oxytetracycline hydrochloride

被引：50

作者：

Lin, Huiting ^{[1
]}

Qiu, Shijie ^{[1
]}

Wu, Zhihao ^{[1
]}

Ye, Xiaoxia ^{[1
]}

Liu, Minghua ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou, Peoples R China

来源：

JOURNAL OF CLEANER PRODUCTION | 2022年 / 331卷

基金：

中国国家自然科学基金;

关键词：

Lignin; Biochar; Multi-metal ferrite; Oxytetracycline hydrochloride; Adsorption mechanism; ORGANIC POLLUTANTS; AQUEOUS-SOLUTION; ADSORPTION; TETRACYCLINE; CARBON; WATER; NANOCOMPOSITE; PARAMETERS; MECHANISM; ADSORBENT;

D O I：

10.1016/j.jclepro.2021.129885

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Efficient removal of oxytetracycline hydrochloride (OTC) from wastewater is of great significance but extremely challenging. Herein, a novel adsorbent lignin-based multi-metal ferrite biochar (FeNiZn-LBC) was synthesized through pyrolysis with controllable temperature and hydrothermal reaction using lignin of sinocalamus oldhami as raw material. The adsorption property of FeNiZn-LBC for OTC was systematically researched, and the results displayed that adsorption of FeNiZn-LBC to OTC accorded with the Langmuir model and the equilibrium adsorption capacity was 476 mg g(-1). Notably, FeNiZn-LBC can be regenerated with 0.100 mol L-1 NaOH. Additionally, we raised rational explanations for the mechanisms of adsorption behavior based on the zeta potential and XPS spectra. The adsorption of FeNiZn-LBC for OTC was mainly controlled by the electrostatic interactions, hydrogen bonds and complexation involving FeNiZn-LBC and OTC, especially the metal-oxide bond (M-O) generated after loaded with multi-metal ferrite played a positive role in the removal of OTC from water. Our work highlighted the potential of FeNiZn-LBC for excellent adsorption of OTC in next generation.

引用

页数：9

共 68 条

[1] Magnetic nickel zinc ferrite nanocomposite as an efficient adsorbent for the removal of organic dyes from aqueous solutions [J].

Afkhami, Abbas ;

Sayari, Shadieh ;

Moosavi, Razieh ;

Madrakian, Tayyebeh .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 21 :920-924

[2] Capabilities of nickel zinc ferrite and its nanocomposite with CNT for adsorption of arsenic (V) ions from wastewater [J].

Ahangari, A. ;

Raygan, Sh ;

Ataie, A. .

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2019, 7 (06)

[3] Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater [J].

Ambaye, T. G. ;

Vaccari, M. ;

van Hullebusch, E. D. ;

Amrane, A. ;

Rtimi, S. .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2021, 18 (10) :3273-3294

[4] Study on photocatalytic degradation of pharmaceutical wastewater by heteropoly acid silver photocatalytic oxidation [J].

An, Changwei ;

Zhang, Danfeng ;

Liu, Tong ;

Yan, Jingsen ;

Yongsheng, E. ;

Dai, Wenshuang ;

Feng, Yue .

2018 4TH INTERNATIONAL CONFERENCE ON ENVIRONMENTAL SCIENCE AND MATERIAL APPLICATION, 2019, 252

[5] Removal of zinc metal ion (Zn2+) from its aqueous solution by kaolin clay mineral: A kinetic and equilibrium study [J].

Arias, Francisco ;

Sen, Tushar Kanti .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 348 (1-3) :100-108

[6] Production and Application of Lignosulfonates and Sulfonated Lignin [J].

Aro, Thomas ;

Fatehi, Pedram .

CHEMSUSCHEM, 2017, 10 (09) :1861-1877

[7] Functionalizing non-smectic clay via methoxy-modification for enhanced removal and recovery of oxytetracycline from aqueous media [J].

Ashiq, Ahmed ;

Walpita, Janitha ;

Vithanage, Meththika .

CHEMOSPHERE, 2021, 276

[8] Treatment of persistent organic pollutants in wastewater using hydrodynamic cavitation in synergy with advanced oxidation process [J].

Badmus, Kassim Olasunkanmi ;

Tijani, Jimoh Oladejo ;

Massima, Emile ;

Petrik, Leslie .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (08) :7299-7314

[9] Ammoxidation of polyethylene: A new route to carbon [J].

Barton, Bryan E. ;

Hukkanen, Eric J. ;

Billovits, Gerry F. ;

Schlader, David ;

Behr, Michael J. ;

Yancey, David ;

Rickard, Mark ;

Qiu, XiaoHua ;

Mowery, Daniel M. ;

Brehm, Lora ;

Haskins, Bryan ;

Wang, Weijun ;

Spalding, Mark S. ;

Derstine, Chris .

CARBON, 2018, 130 :288-294

[10] Adsorption of Zn(II) from aqueous solution by using different adsorbents [J].

Bhattacharya, A. K. ;

Mandal, S. N. ;

Das, S. K. .

CHEMICAL ENGINEERING JOURNAL, 2006, 123 (1-2) :43-51

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