Reaching the south: metal-catalyzed transformation of the aromatic para-position

被引：118

作者：

Dey, Aniruddha ^{[1
]}

Maity, Soham ^{[1
]}

Maiti, Debabrata ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay, Maharashtra, India

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 84期

关键词：

C-H ACTIVATION; N BOND FORMATION; NICKEL/LEWIS ACID CATALYSIS; ELECTRON-RICH ARENES; DIRECT ARYLATION; INSERTION REACTIONS; GOLD CATALYSIS; ENANTIOSELECTIVE SYNTHESIS; MULTISUBSTITUTED ARENES; SELECTIVE ALKENYLATION;

D O I：

10.1039/c6cc05235e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regioselective functionalization of aromatic arenes has created a rapid insurgence in the modern era of organic chemistry. While the last few years have witnessed significant developments on site-selective ortho-and meta-C-H transformations, there existed very few reports on para-C-H functionalization. Recent advancements on template assisted protocols in para-C-H activation has emerged as a popular and convenient feat in this area. This review highlights the various protocols developed over the years for selective installation of suitable functional groups at the para-position of arenes thereby transforming them into value-added organic cores.

引用

页码：12398 / 12414

页数：17

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