Ethyl 2-[N-(tert-butylsulfinyl)carbamoyl]benzoate

被引:1
|
作者
Honraedt, Aurelien [1 ,2 ]
Ladeira, Sonia [1 ,2 ]
Berranger, Thierry [3 ]
Gras, Emmanuel [1 ,2 ]
机构
[1] CNRS, LCC, F-31077 Toulouse, France
[2] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
[3] Minakem, F-59310 Beuvry La Foret, France
关键词
ORGANIC-COMPOUNDS; PATTERNS;
D O I
10.1107/S1600536811047027
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C14H19NO4S, was obtained in quantitative yield by Lewis acid-catalysed alcoholysis of a phtalimide precursor. An intramolecular C-H center dot center dot center dot O hydrogen bond occurs. In the crystal, centrosymmetric dimers are formed by pairs of N-H center dot center dot center dot O hydrogen bonds between the sulfinyl O atoms and the carbamoyl N-H group of a neighboring molecule. C-H center dot center dot center dot O interactions feature in the crystal structure.
引用
收藏
页码:O3350 / U889
页数:10
相关论文
共 50 条
  • [1] A straightforward green synthesis of N-(tert-butylsulfinyl)imines
    Lv, Xirui
    Zhou, Yue
    Zhang, Anguo
    Zhou, Lihong
    Zeng, Qingle
    TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 2016, 98 (10): : 1155 - 1162
  • [2] Synthesis of γ-, δ-, and ε-Lactams by Asymmetric Transfer Hydrogenation of N-(tert-Butylsulfinyl)iminoesters
    Guijarro, David
    Pablo, Oscar
    Yus, Miguel
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (08): : 3647 - 3654
  • [3] Diastereoselective Hydrosilylation of N-(tert-Butylsulfinyl)imines Catalyzed by Zinc Acetate
    Adamkiewicz, Anna
    Mlynarski, Jacek
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (05) : 1060 - 1065
  • [4] Ethyl 2-{N-[N-(4-chloro-6-methoxypyrimidin-2-yl)carbamoyl]sulfamoyl}benzoate
    Lu, Chui
    Li, Fang-Shi
    Yu, Da-Sheng
    Yao, Wei
    Liu, Yin-Hong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1248 - U1757
  • [5] Stereoselective Mannich Reaction of N-(tert-Butylsulfinyl) imines with 3-Fluorooxindoles and Fluoroacetamides
    Chen, Xiangyu
    Li, Ya
    Zhao, Jianbo
    Zheng, Buquan
    Lu, Qi
    Ren, Xinfeng
    ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (17) : 3057 - 3062
  • [6] Diastereoselective cyanomethylation of chiral N-(tert-butylsulfinyl)imines promoted by lewis bases
    Mukaiyama, Teruaki
    Michida, Makoto
    CHEMISTRY LETTERS, 2007, 36 (10) : 1244 - 1245
  • [7] Microwave-Enhanced Asymmetric Transfer Hydrogenation of N-(tert-Butylsulfinyl)imines
    Pablo, Oscar
    Guijarro, David
    Yus, Miguel
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (31) : 7034 - 7038
  • [8] Stereoselective nucleophilic trifluoromethylation of N-(tert-butylsulfinyl)imines by using trimethyl(trifluoromethyl)silane
    Prakash, GKS
    Mandal, M
    Olah, GA
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (03) : 589 - 590
  • [9] Facile synthesis of chiral α-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines
    Li, Y
    Hu, JB
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (36) : 5882 - 5886
  • [10] Synthesis of Nitrogenated Heterocycles by Asymmetric Transfer Hydrogenation of N-(tert-Butylsulfinyl)haloimines
    Pablo, Oscar
    Guijarro, David
    Yus, Miguel
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (18): : 9181 - 9189