Template synthesis and single-molecule magnetism properties of a complex with spin S=16 and a [Mn8O8]8+ saddle-like core

被引：87

作者：

Tasiopoulos, AJ

Wernsdorfer, W

Moulton, B

Zaworotko, MJ

Christou, G ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] CNRS, Lab Louis Neel, F-38042 Grenoble, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 50期

关键词：

GROUND-STATE; MAGNETIZATION; CLUSTER;

D O I：

10.1021/ja0385134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound [CeIVMn8IIIO8(O2CMe)12(H2O)4]·4H2O (1·4H2O) has been obtained from a template synthesis involving the reaction of the chain polymer {[MnIII(OH)(O2CMe)2]·(MeCO2H)·(H2O)}n (3) with Ce(IV). Compound 1 contains a Mn8III loop inside which is held the Ce(IV) ion by the bridging oxide ions. Magnetization and magnetic susceptibility studies establish that 1 has an S = 16 spin ground state, the largest yet for a Mn cluster, and displays the slow magnetization relaxation and hysteresis behavior of a single-molecule magnet (SMM). It is thus the highest spin Mn SMM discovered to date. Copyright © 2003 American Chemical Society.

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页码：15274 / 15275

页数：2

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