Bis[alkynylplatinum(II)] Terpyridine Molecular Tweezer/Guest Recognition Enhanced by Intermolecular Hydrogen Bonds: Phototriggered Complexation via the "Caging" Strategy

被引:21
作者
Fu, Tengfei [1 ]
Han, Yifei [1 ]
Ao, Lei [1 ]
Wang, Feng [1 ]
机构
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, IChEM Collaborat Innovat Ctr Chem Energy Mat, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
HOST-GUEST INTERACTIONS; SUPRAMOLECULAR POLYMERIZATION; ASTERISK-ASTERISK; POLYMERS; RELEASE; SYSTEM; MOTIF;
D O I
10.1021/acs.organomet.6b00429
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The binding affinity between alkynylplatinum(II) terpyridine molecular tweezer and naphthol-derived guests can be significantly enhanced by embedding an intermolecular O-H---N hydrogen bond, facilitating the achievement of a responsive host-guest recognition system via the photolabile "caging" strategy.
引用
收藏
页码:2850 / 2853
页数:4
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