Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates

被引:376
作者
Chrusciel, Jerzy J. [1 ,2 ]
Lesniak, Elzbieta [1 ]
机构
[1] Lodz Univ Technol, Fac Chem, Inst Polymer & Dye Technol, PL-90924 Lodz, Poland
[2] Text Res Inst, PL-92103 Lodz, Poland
关键词
Epoxy resins; Silane coupling agents; Polysiloxanes; Silsesquioxanes; Silica; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; ORGANIC-INORGANIC HYBRIDS; CYCLOALIPHATIC SUBSTITUENTS GROUPS; SOL-GEL MATERIALS; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; FLAME-RETARDANT; THERMOMECHANICAL PROPERTIES; DIELECTRIC-PROPERTIES; CORROSION PROTECTION;
D O I
10.1016/j.progpolymsci.2014.08.001
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Epoxy resins are very important and widely used thermosetting polymers that find many practical applications. Very often their properties can be effectively modified by an addition of reactive silanes, polysiloxanes, silsesquioxanes, silica, montmorillonite, and other fillers. This review considers the literature concerning: (a) synthesis of carbofunctional silanes (CFS), polysiloxanes (CFPS) and polyhedral silsesquioxanes (POSS); (b) properties of neat epoxy resins and their composites and nanocomposites, obtained by modifications with reactive silanes, silicon containing monomers and polymers, and silica based fillers, enabling improvement of their mechanical properties, thermal and flame resistance as well as providing corrosion and antimicrobial protection. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:67 / 121
页数:55
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