Hydrogen Generation from Formic Acid Decomposition by Ruthenium Carbonyl Complexes. Tetraruthenium Dodecacarbonyl Tetrahydride as an Active Intermediate

被引：74

作者：

Czaun, Miklos ^{[1
]}

Goeppert, Alain ^{[1
]}

May, Robert ^{[1
]}

Haiges, Ralf ^{[1
]}

Prakash, G. K. Surya ^{[1
]}

Olah, George A. ^{[1
]}

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

来源：

CHEMSUSCHEM | 2011年 / 4卷 / 09期

基金：

美国能源部;

关键词：

carbon dioxide; formic acid; homogeneous catalysis; hydrogen storage; ruthenium; GAS SHIFT REACTION; HOMOGENEOUS CATALYSIS; STORAGE MATERIAL; METAL-CARBONYLS; DIOXIDE; FORMATE; CO2; REACTIVITY; HYDRIDES; CAPTURE;

D O I：

10.1002/cssc.201000446

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present Minireview covers the formation and the structural characterization of noble metal carbonyl and hydrido carbonyl complexes, with particular emphasis on ruthenium complexes using formic acid as a carbonyl and hydride source. The catalytic activity of these organometallic compounds for the decarboxylation of formic acid, a potential hydrogen storage material, is also reviewed. In addition, the first preparation of [Ru-4(CO)(12)H-4] from RuCl3 and formic acid as well as the catalytic activity of [Ru-4(CO)(12)H-4] for the decomposition of formic acid to hydrogen and carbon dioxide are presented.

引用

页码：1241 / 1248

页数：8

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