Thermodynamic Properties of Plant Biomass Components. Heat Capacity, Combustion Energy, and Gasification Equilibria of Cellulose

被引：52

作者：

Blokhin, Andrey V.

Voitkevich, Olga V.

Kabo, Gennady J. ^{[1
]}

Paulechka, Yauheni U.

Shishonok, Margarita V.

Kabo, Andrey G.

Simirsky, Vladimir V.

机构：

[1] Belarusian State Univ, Fac Chem, Leningradskaya 14, Minsk 220030, BELARUS

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 09期

关键词：

D O I：

10.1021/je200270t

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Heat capacities and enthalpies of formation were determined for the well-characterized samples of cellulose of different origins. The obtained experimental results allowed us to obtain the accurate values of thermodynamic properties for this material. It was demonstrated that the heat capacity and entropy of cellulose samples can be linearly related with their crystallinity index. The equilibria of the processes of cellulose gasification were considered. The adiabatic temperatures of the gasification and energetic characteristics of the products of cellulose thermolysis were evaluated.

引用

页码：3523 / 3531

页数：9

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