Effect of different templates on structure evolution and large strain response under a low electric field in ⟨001⟩-textured lead-free BNT-based piezoelectric ceramics

被引:84
作者
Bai, Wangfeng [1 ]
Xi, Junhua [1 ]
Zhang, Jun [1 ]
Shen, Bo [2 ]
Zhai, Jiwei [2 ]
Yan, Haixue [3 ]
机构
[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Zhejiang, Peoples R China
[2] Tongji Univ, Funct Mat Res Lab, Shanghai 200092, Peoples R China
[3] Queen Mary Univ London, Sch Engn & Mat Sci, London E1 4NS, England
基金
中国国家自然科学基金;
关键词
Templated grain growth; Na0.5Bi0.5TiO3 textured ceramics; Strain response; Lead-free ceramics; NA0.5BI0.5TIO3-BATIO3; CERAMICS; GRAIN-GROWTH; MICROSTRUCTURE; PEROVSKITES;
D O I
10.1016/j.jeurceramsoc.2015.03.016
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
< 001 >-textured 0.83Na(0.5)Bi(0.5)TiO(3)-0.17Bi(0.5)K(0.5)TiO(3) (BNT-BKT) ceramics with high degree of texturing (>80%) were synthesized by templated grain growth using different perovskite plate-like BaTiO3, SrTiO3 and NaNbO3 as template particles to develop lead-free piezoelectric materials with an excellent actuating performance. The effects of different template particles addition to BNT-BKT ceramics on the grain orientation, structure evolution, phase stability and macroscopic functional properties was systematically investigated. BaTiO3 template particles addition to form < 001 >-textured BNT-BKT-BT textured ceramics suppresses an electric-field-induced long-range ferroelectric order, giving rise to a high field-induced S-max/E-max of 710 pm/V under a relatively low driving field of 45 kV/cm compared with existing lead-free Bi-perovskite ceramics. In particular, temperature-dependent strain response reveals that < 001 >-textured BNT-BKT-5BT ceramics exhibit not only large S-max/E-max at a low driving field of 45 kV/cm at room temperature but also enhanced the temperature stability of S-max/E-max featured by large S-max/E-max of 517 pm/V at high temperature. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2489 / 2499
页数:11
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