Anion complexation by amido derivatives of p-tert-butyl calix[4]arene

被引:13
作者
Hamdi, Abdelwaheb [1 ,3 ]
Abidi, Rym [2 ]
Vicens, Jacques [3 ]
机构
[1] Univ El Manar Tunis, ISTMT, Tunis 1006, Tunisia
[2] Univ 7 Novembre Carthage, Fac Sci Bizerte, Carthage, Tunisia
[3] Univ Strasbourg, ECPM, Lab Concept Mol, F-67087 Strasbourg, France
关键词
calixarenes; anion complexation; H-1; NMR;
D O I
10.1007/s10847-007-9346-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The binding properties of 1,2,3,4-amido derivatives of p-tert-butyl calix[4]arene (4-6) towards various anions (spherical halides, planar trigonal nitrate and tetrahedral hydrogen sulphate) as their tetrabutyl ammonium (TBA) salts have been studied by H-1 NMR technique and using Equi Chem program. The stability constants, log K-ass, varying from 0.76 +/- 0.10 to 2.13 +/- 0.04 have been determined for the mononuclear complexes.
引用
收藏
页码:193 / 196
页数:4
相关论文
共 25 条
[11]  
Gutsche C. D, 1998, MONOGRAPHS SUPRAMOLE
[12]  
Hamdi A, 2003, J INCL PHENOM MACRO, V45, P99
[13]  
Hofmeister F., 1888, Arch. Exp. Pathol. Pharmakol, V24, P247, DOI DOI 10.1007/BF01918191
[14]  
Ilioudis CA, 2001, J SUPRAMOL CHEM, V1, P165, DOI DOI 10.1016/S1472-7862(02)00026-6
[15]   Amide-based ligands for anion coordination [J].
Kang, Sung Ok ;
Begum, Rowshan Ara ;
Bowman-James, Kristin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (47) :7882-7894
[16]   Recognition of anions by synthetic receptors in aqueous solution [J].
Kubik, S ;
Reyheller, C ;
Stüwe, S .
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 52 (3-4) :137-187
[17]  
LUMETTA GJ, 2000, CALIXARENES SEPARATI
[18]  
MAHOUACHI M, 2005, JNBT, V2, P47
[19]  
Mandolini L., 2000, CALIXARENES ACTION I
[20]  
Matthews SE, 2001, CALIXARENES 2001, P421