Anion complexation by amido derivatives of p-tert-butyl calix[4]arene

被引:13
作者
Hamdi, Abdelwaheb [1 ,3 ]
Abidi, Rym [2 ]
Vicens, Jacques [3 ]
机构
[1] Univ El Manar Tunis, ISTMT, Tunis 1006, Tunisia
[2] Univ 7 Novembre Carthage, Fac Sci Bizerte, Carthage, Tunisia
[3] Univ Strasbourg, ECPM, Lab Concept Mol, F-67087 Strasbourg, France
关键词
calixarenes; anion complexation; H-1; NMR;
D O I
10.1007/s10847-007-9346-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The binding properties of 1,2,3,4-amido derivatives of p-tert-butyl calix[4]arene (4-6) towards various anions (spherical halides, planar trigonal nitrate and tetrahedral hydrogen sulphate) as their tetrabutyl ammonium (TBA) salts have been studied by H-1 NMR technique and using Equi Chem program. The stability constants, log K-ass, varying from 0.76 +/- 0.10 to 2.13 +/- 0.04 have been determined for the mononuclear complexes.
引用
收藏
页码:193 / 196
页数:4
相关论文
共 25 条
[1]  
[Anonymous], 1989, MONOGRAPHS SUPRAMOLE
[2]   Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems [J].
Beer, PD .
CHEMICAL COMMUNICATIONS, 1996, (06) :689-696
[3]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[4]  
2-G
[5]   Amide based receptors for anions [J].
Bondy, CR ;
Loeb, SJ .
COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :77-99
[6]  
Casnati A, 2001, CALIXARENES 2001, P365
[7]  
da Silva JJR Frausto., 1991, BIOL CHEM ELEMENTS
[8]   A SODIUM ION-SELECTIVE ELECTRODE BASED ON METHYL PARA-TERT-BUTYLCALIX[4]ARYL ACETATE AS THE IONOPHORE [J].
DIAMOND, D ;
SVEHLA, G ;
SEWARD, EM ;
MCKERVEY, MA .
ANALYTICA CHIMICA ACTA, 1988, 204 (1-2) :223-231
[9]   DESIGN OF ANION RECEPTORS - APPLICATIONS [J].
DIETRICH, B .
PURE AND APPLIED CHEMISTRY, 1993, 65 (07) :1457-1464
[10]   Special issue: 35 years of synthetic anion receptor chemistry 1968-2003 - Preface [J].
Gale, PA .
COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :1-1