Density measurement of liquid FeS at high pressures using synchrotron X-ray absorption

被引:32
作者
Nishida, Keisuke [1 ]
Ohtani, Eiji [1 ]
Urakawa, Satoru [2 ]
Suzuki, Akio [1 ]
Sakamaki, Tatsuya [1 ]
Terasaki, Hidenori [1 ]
Katayama, Yoshinori [3 ]
机构
[1] Tohoku Univ, Dept Earth & Planetary Mat Sci, Sendai, Miyagi 9808578, Japan
[2] Okayama Univ, Dept Earth Sci, Okayama 7008530, Japan
[3] Japan Atom Energy Agcy, Hyogo 6795143, Japan
基金
日本学术振兴会;
关键词
X-ray absorption method; liquid FeS; density; high pressure; equation of state; MAGNETIC-FIELD; INTERNAL STRUCTURE; THERMAL-EXPANSION; STATE; MARS; TEMPERATURE; MERCURY; COEFFICIENTS; ATTENUATION; PYRRHOTITE;
D O I
10.2138/am.2011.3616
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The density of liquid iron sulfide (FeS) was measured up to 3.8 GPa and 1800 K using an X-ray absorption method. The compression curve of liquid FeS was fitted using the Vinet equation of state. The isothermal bulk modulus and its temperature and pressure derivatives were determined using a nonlinear least-squares fit. The parameter sets determined were: K(0T) = 2.5 +/- 0.3 GPa at T = 1500 K, (dK(0)/dT)(P) = 0.0036 +/- 0.0003 GPa/K, and (dK(0)/dP)(T) = 24 +/- 2. These results suggest that liquid FeS is more compressible than Fe-rich liquid Fe-S.
引用
收藏
页码:864 / 868
页数:5
相关论文
共 39 条
[1]   Global distribution of crustal magnetization discovered by the Mars Global Surveyor MAG/ER experiment [J].
Acuña, MH ;
Connerney, JEP ;
Ness, NF ;
Lin, RP ;
Mitchell, D ;
Carlson, CW ;
McFadden, J ;
Anderson, KA ;
Rème, H ;
Mazelle, C ;
Vignes, D ;
Wasilewski, P ;
Cloutier, P .
SCIENCE, 1999, 284 (5415) :790-793
[2]   Equation of state of liquid Fe-10 wt % S: Implications for the metallic cores of planetary bodies [J].
Balog, PS ;
Secco, RA ;
Rubie, DC ;
Frost, DJ .
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH, 2003, 108 (B2)
[3]   Density measurements of liquids at high pressure: Modifications to the sink/float method by using composite spheres, and application to Fe-10wt%S [J].
Balog, PS ;
Secco, RA ;
Rubie, DC .
HIGH PRESSURE RESEARCH, 2001, 21 (05) :237-261
[4]   ELASTICITY AND CONSTITUTION OF THE EARTH INTERIOR [J].
BIRCH, F .
JOURNAL OF GEOPHYSICAL RESEARCH, 1952, 57 (02) :227-286
[5]   MELTING RELATIONS IN FE-RICH PORTION OF SYSTEM FE-FES AT 30-KB PRESSURE [J].
BRETT, R ;
BELL, PM .
EARTH AND PLANETARY SCIENCE LETTERS, 1969, 6 (06) :479-&
[6]   Interior evolution of Mercury [J].
Breuer, Doris ;
Hauck, Steven A., II ;
Buske, Monika ;
Pauer, Martin ;
Spohn, Tilman .
SPACE SCIENCE REVIEWS, 2007, 132 (2-4) :229-260
[7]   THEORETICAL FORM-FACTOR, ATTENUATION AND SCATTERING TABULATION FOR Z=1-92 FROM E=1-10 EV TO E=0.4-1.0 MEV [J].
CHANTLER, CT .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1995, 24 (01) :71-591
[8]  
Chen J., 2005, ADV HIGH PRESSURE TE, P185
[9]   Tectonic implications of Mars crustal magnetism [J].
Connerney, JEP ;
Acuña, MH ;
Ness, NF ;
Kletetschka, G ;
Mitchell, DL ;
Lin, RP ;
Reme, H .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (42) :14970-14975
[10]   X-RAY INTERACTIONS - PHOTOABSORPTION, SCATTERING, TRANSMISSION, AND REFLECTION AT E=50-30,000 EV, Z=1-92 [J].
HENKE, BL ;
GULLIKSON, EM ;
DAVIS, JC .
ATOMIC DATA AND NUCLEAR DATA TABLES, 1993, 54 (02) :181-342