Simultaneous Interfacial Modification and Defect Passivation for Wide-Bandgap Semitransparent Perovskite Solar Cells with 14.4% Power Conversion Efficiency and 38% Average Visible Transmittance

被引：23

作者：

Shi, Hongxi ^{[1
]}

Zhang, Lei ^{[1
]}

Huang, Hao ^{[1
]}

Wang, Xiaoting ^{[1
]}

Li, Ziyu ^{[1
]}

Xuan, Dazhi ^{[1
]}

Wang, Chenyu ^{[1
]}

Ou, Yali ^{[1
]}

Ni, Chaojie ^{[1
]}

Li, Denggao ^{[1
]}

Chi, Dan ^{[1
]}

Huang, Shihua ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Prov Key Lab Solid State Optoelect Devices, Jinhua 321004, Zhejiang, Peoples R China

来源：

SMALL | 2022年 / 18卷 / 31期

基金：

国家重点研发计划;

关键词：

defect passivation; high average visible transmittance; interfacial modification; semitransparent perovskite solar cells; wide-bandgap perovskite; GROWTH;

D O I：

10.1002/smll.202202144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perovskite materials offer a great potential in the application of semitransparent solar cells, owing to the tunable bandgap, ease of preparation and excellent photovoltaic property. A majority of works exhibit high average visible-light transmittance (AVT) for semitransparent perovskite solar cells (ST-PSCs) through decreasing perovskite thickness, leading to sacrificing the power conversion efficiency (PCE) of the device. Herein, a wide-bandgap (WBG) perovskite of Cs(0.2)FA(0.8)Pb(I0.6Br0.4)(3) is applied as absorber in ST-PSCs, which is a tremendous progress to balance both large PCE and high AVT. Moreover, a strategy of simultaneous interfacial modification and defect passivation is provided to enhance the performance of WBG ST-PSCs. Consequently, an inverted planar structure WBG perovskite solar cell (PSC) achieves 15.06% of PCE with excellent stability by restraining the interfacial energy loss and suppressing the nonradiative recombination. Furthermore, the ST-PSC obtains high PCE of 14.40% with an AVT of 38% by means of optimizing the transparent electrode. This work provides an efficient and simple method to improve the performance and AVT of ST-PSCs for the application in building-integrated photovoltaics.

引用

收藏

页数：11

相关论文

共 56 条

[1] Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells [J].

Al-Ashouri, Amran ;

Magomedov, Artiom ;

Ross, Marcel ;

Jost, Marko ;

Talaikis, Martynas ;

Chistiakova, Ganna ;

Bertram, Tobias ;

Marquez, Jose A. ;

Kohnen, Eike ;

Kasparavicius, Ernestas ;

Levcenco, Sergiu ;

Gil-Escrig, Lidon ;

Hages, Charles J. ;

Schlatmann, Rutger ;

Rech, Bernd ;

Malinauskas, Tadas ;

Unold, Thomas ;

Kaufmann, Christian A. ;

Korte, Lars ;

Niaura, Gediminas ;

Getautis, Vytautas ;

Albrecht, Steve .

ENERGY & ENVIRONMENTAL SCIENCE, 2019, 12 (11) :3356-3369

[2] Efficient semi-transparent planar perovskite solar cells using a 'molecular glue' [J].

Bag, Santanu ;

Durstock, Michael F. .

NANO ENERGY, 2016, 30 :542-548

[3] Managing transparency through polymer/perovskite blending: A route toward thermostable and highly efficient, semi-transparent solar cells [J].

Bisconti, Francesco ;

Giuri, Antonella ;

Dominici, Lorenzo ;

Carallo, Sonia ;

Quadrivi, Eleonora ;

Po, Riccardo ;

Biagini, Paolo ;

Listorti, Andrea ;

Corcione, Carola Esposito ;

Colella, Silvia ;

Rizzo, Aurora .

NANO ENERGY, 2021, 89 (89)

[4] Thermal and Environmental Stability of Semi-Transparent Perovskite Solar Cells for Tandems Enabled by a Solution-Processed Nanoparticle Buffer Layer and Sputtered ITO Electrode [J].

Bush, Kevin A. ;

Bailie, Colin D. ;

Chen, Ye ;

Bowring, Andrea R. ;

Wang, Wei ;

Ma, Wen ;

Leijtens, Tomas ;

Moghadam, Farhad ;

McGehee, Michael D. .

ADVANCED MATERIALS, 2016, 28 (20) :3937-+

[5] Perovskite photovoltachromic cells for building integration [J].

Cannavale, Alessandro ;

Eperon, Giles E. ;

Cossari, Pierluigi ;

Abate, Antonio ;

Snaith, Henry J. ;

Gigli, Giuseppe .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) :1578-1584

[6] High-Performance Tin-Lead Mixed-Perovskite Solar Cells with Vertical Compositional Gradient [J].

Cao, Jiupeng ;

Hok-Leung Loi ;

Xu, Yang ;

Guo, Xuyun ;

Wang, Naixiang ;

Liu, Chun-ki ;

Wang, Tianyue ;

Cheng, Haiyang ;

Zhu, Ye ;

Li, Mitch Guijun ;

Wai-Yeung Wong ;

Yan, Feng .

ADVANCED MATERIALS, 2022, 34 (06)

[7] Interfacial engineering of a thiophene-based 2D/3D perovskite heterojunction for efficient and stable inverted wide-bandgap perovskite solar cells [J].

Chen, Cong ;

Liang, Jiwei ;

Zhang, Junjun ;

Liu, Xinxing ;

Yin, Xinxing ;

Cui, Hongsen ;

Wang, Haibing ;

Wang, Chen ;

Li, Zaifang ;

Gong, Junbo ;

Lin, Qianqian ;

Ke, Weijun ;

Tao, Chen ;

Da, Bo ;

Ding, Zejun ;

Xiao, Xudong ;

Fang, Guojia .

NANO ENERGY, 2021, 90

[8] Multidentate passivation crosslinking perovskite quantum dots for efficient solar cells [J].

Chen, Jingxuan ;

Jia, Donglin ;

Qiu, Junming ;

Zhuang, Rongshan ;

Hua, Yong ;

Zhang, Xiaoliang .

NANO ENERGY, 2022, 96

[9] High performance wide bandgap Lead-free perovskite solar cells by monolayer engineering [J].

Chen, Mengmeng ;

Kapil, Gaurav ;

Wang, Liang ;

Sahamir, Shahrir Razey K. ;

Baranwal, Ajay ;

Nishimura, Kohei ;

Sanehira, Yoshitaka ;

Zhang, Zheng ;

Kamarudin, Muhammad Akmal ;

Shen, Qing ;

Hayase, Shuzi .

CHEMICAL ENGINEERING JOURNAL, 2022, 436

[10] Mixed 3D-2D Passivation Treatment for Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells for Higher Efficiency and Better Stability [J].

Cho, Yongyoon ;

Soufiani, Arman Mahboubi ;

Yun, Jae Sung ;

Kim, Jincheol ;

Lee, Da Seul ;

Seidel, Jan ;

Deng, Xiaofan ;

Green, Martin A. ;

Huang, Shujuan ;

Ho-Baillie, Anita W. Y. .

ADVANCED ENERGY MATERIALS, 2018, 8 (20)

← 1 2 3 4 5 6 →