Effect of the metal-assisted assembling mode on the redox states of hexaazatriphenylene hexacarbonitrile

被引：55
作者：
Furukawa, S
Okubo, T
Masaoka, S
Tanaka, D
Chang, HC
Kitagawa, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] JAIST, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 18期
关键词：
D O I：
10.1002/anie.200462962
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) If the hat fits: The size of the ferrocene coligands used during the self-asssembly of hexaazatriphenylene hexacarbonitrile (hat-(CN)6) with CuI ions determines the coordination mode of the hat-(CN)6 ligand (bipyridine chelation or monodentate CN, see picture). The mode of coordination directly affects the oxidation state and the reduction potentials of the Hat-(CN)6 ligand. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：2700 / 2704
页数：5
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