Constituents of Cydonia vulgaris: Isolation and structure elucidation of four new flavonol glycosides and nine new alpha-ionol-derived glycosides

被引:27
作者
DeTommasi, N
Piacente, S
DeSimone, F
Pizza, C
机构
[1] UNIV SALERNO, CTR INTERDIPARTIMENTAL CHIM BIOL & TECNOL FARMACEU, I-84100 SALERNO, ITALY
[2] UNIV NAPLES FEDERICO II, DIPARTIMENTO CHIM SOSTANZE NAT, I-80131 NAPLES, ITALY
关键词
Cydonia vulgaris; Rosaceae; flavonol glycosides; alpha-ionol glycosides; H-1 and C-13 NMR;
D O I
10.1021/jf950547a
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
In a previous paper, we described the isolation of four new sesterterpenes from Cydonia vulgaris Pers. Here we report the isolation of four new flavonol glycosides (1-4) and nine new a-ionol derived glycosides (5-13) together with the known 3-oxo-alpha-ionol 9-O-beta-D-apiofuranosyl-(1-->6)-beta-D-glucopyranoside (14), vomifoliol 9-O-beta-n-glucopyranoside (roseoside) (15), and vomifoliol 9-O-beta-D-apiofuranosyl-(1-->6)-beta-D-glucopyranoside,id (16) from the MeOH extract of the aerial parts of C. vulgaris Pers, (Rosaceae). All structures were elucidated by spectroscopic methods, including the concerted application of one-dimensional NMR and two-dimensional NMR techniques (COSY-90 and HET-COR).
引用
收藏
页码:1676 / 1681
页数:6
相关论文
共 13 条
[11]   TOBACCO CHEMISTRY .38. EFFECTS OF FLUE-CURING AND AGING ON VOLATILE, NEUTRAL AND ACIDIC CONSTITUENTS OF VIRGINIA TOBACCO [J].
WAHLBERG, I ;
KARLSSON, K ;
AUSTIN, DJ ;
JUNKER, N ;
ROERAADE, J ;
ENZELL, CR ;
JOHNSON, WH .
PHYTOCHEMISTRY, 1977, 16 (08) :1217-1231
[12]  
WILLIAMS PJ, 1993, RECENT DEV FLAVOR FR, P283
[13]  
WINTERHALTER P, 1992, ACS SYM SER, V490, P98