A Facile Chemical Precipitation Method for the Synthesis of Nd(OH)3 and La(OH)3 Nanopowders and their Supercapacitor Performances

被引:47
作者
Arunachalam, Subasri [1 ,2 ]
Kirubasankar, Balakrishnan [1 ]
Nagarajan, Erumaipatty Rajagounder [2 ]
Vellasamy, Devadoss [2 ]
Angaiah, Subramania [1 ]
机构
[1] Pondicherry Univ, Electromat Res Lab, Ctr Nanosci & Technol, Pondicherry 605014, India
[2] Kalasalingam Univ, Dept Chem, Krishnankovil 626126, India
关键词
Asymmetric supercapacitor; Lanthanum hydroxide; Neodymium hydroxide; Precipitation method; Rare-earth hydroxide; ELECTRODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; GRAPHENE NANOSHEETS; RATE CAPABILITY; THIN-FILM; CAPACITANCE; NANOHYBRID; NANOFIBERS; OXIDE; COMPOSITE;
D O I
10.1002/slct.201803151
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile chemical precipitation method is used to prepare both lanthanum hydroxide [La(OH)(3)] and neodymium hydroxide [Nd(OH)(3)] nanopowders in an ambient temperature without the addition of any surfactants. Both rare-earth hydroxides nanopowders are characterized by X-ray diffraction and FE-SEM analysis. The supercapacitor performances of La(OH)(3) and Nd(OH)(3) electrodes are studied by cyclic voltammetry, electrochemical AC-impedance and galvanostatic charge-discharge studies. It revealed that Nd(OH)(3) electrode possesses a high specific capacitance (C-sp) than La(OH)(3) electrode. Hence, an asymmetric supercapacitor device is fabricated and denoted as Nd(OH)(3)parallel to AC in 6 M KOH as the electrolyte soaked in the electrospun poly(vinylidene fluoride) membrane as the separator, which exhibited an energy density of 18.8 Wh kg(-1) at a power density of 796 W kg(-1).
引用
收藏
页码:12719 / 12724
页数:6
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