SiC/SiO2 coating for improving the oxidation resistive property of carbon nanofiber

被引:38
作者
Kim, Bo-Hye [2 ]
Kim, Chang Hyo [2 ]
Yang, Kap Seung [1 ,2 ]
Kim, Ki-Young [3 ]
Lee, Young-Jun
机构
[1] Chonnam Natl Univ, Dept Polymer & Fiber Syst Engn, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Alan G MacDiarmid Energy Res Inst, Kwangju 500757, South Korea
[3] Korea Inst Ind Technol, Ansan 426791, South Korea
关键词
Electrospun carbon nanofiber; Oxidation resistance; Sol-gel process; SiC/SiO2; coating; SOL-GEL COATINGS; SILICON-CARBIDE; FIBERS; OXIDE;
D O I
10.1016/j.apsusc.2010.08.104
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The SiC/SiO2 deposition was performed to improve the oxidation resistive properties of carbon nanofiber (CNF) from electrospinning at elevated temperatures through sol-gel process. The stabilized polyacrylonitrile (PAN) fibers were coated with SiO2 followed by heat treatment up to 1000 and 1400 degrees C in an inert argon atmosphere. The chemical compositions of the CNFs surface heat-treated were characterized as C, Si and O existing as SiC and SiO2 compounds on the surface. The uniform and continuous coating improved the oxidation resistance of the carbon nanofibers. The residual weight of the composite was 70-80% and mixture of SiC, SiO2 and some residual carbon after exposure to air at 1000 degrees C. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1607 / 1611
页数:5
相关论文
共 24 条
[1]   PROGRESS IN DEVELOPMENT OF GRAPHITE-ALUMINUM COMPOSITES USING LIQUID INFILTRATION TECHNOLOGY [J].
AMATEAU, MF .
JOURNAL OF COMPOSITE MATERIALS, 1976, 10 (OCT) :279-296
[2]  
Baker A.A., 1971, COMPOSITES, V2, P154, DOI [10.1016/0010-4361(71)90952-9, DOI 10.1016/0010-4361(71)90952-9]
[3]   STOICHIOMETRY OF THE C+SIO2 REACTION [J].
BIERNACKI, JJ ;
WOTZAK, GP .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (01) :122-129
[4]  
Brinker C.J., 1990, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, P881
[5]  
BRINKER CJ, 1990, SOL GEL SCI PHYS CHE, P56
[6]  
CHU PY, 1988, ADV CERAM MATER, V3, P249
[7]   Controlled deposition of electrospun poly(ethylene oxide) fibers [J].
Deitzel, JM ;
Kleinmeyer, JD ;
Hirvonen, JK ;
Tan, NCB .
POLYMER, 2001, 42 (19) :8163-8170
[8]   PROTECTIVE GLASS COATINGS ON METALLIC SUBSTRATES [J].
DESANCTIS, O ;
GOMEZ, L ;
PELLEGRI, N ;
PARODI, C ;
MARAJOFSKY, A ;
DURAN, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 121 (1-3) :338-343
[9]   Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592
[10]   The synthesis of SiC and TiC protective coatings for carbon fibers by the reactive replica process [J].
Gadiou, R. ;
Serverin, S. ;
Gibot, P. ;
Vix-Guterl, C. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2008, 28 (11) :2265-2274