Copper(II) Triflate-Catalyzed Three-Component Coupling of Aldehydes, Alkynes and Carbamates

被引：16
作者：
Dou, Xiao-Yong [1 ,2 ,3 ]
Qi Shuai [3 ]
He, Liang-Nian [1 ,2 ]
Li, Chao-Jun [3 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[3] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 14-15期
基金：
加拿大自然科学与工程研究理事会;
关键词：
A(3)-coupling; aldehydes; alkynes; carbamates; copper(II) triflate; HIGHLY ENANTIOSELECTIVE SYNTHESIS; C-H ACTIVATION; TERMINAL ALKYNES; DIRECT-ADDITION; STEREOREGULAR POLY(N-PROPARGYLCARBAMATES); ASYMMETRIC ADDITION; GLYCINE DERIVATIVES; N-PROPARGYLAMIDES; AMINES; IMINES;
D O I：
10.1002/adsc.201000379
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A simple and efficient synthesis of propargylcarbamates was developed through a copper(II) triflate-catalyzed coupling of aldehydes, alkynes and carbamates. No co-catalyst or ligand is required.
引用
收藏
页码：2437 / 2440
页数：4
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