Full-Color and White Circularly Polarized Luminescence Promoted by Liquid Crystal Self-Assembly Containing Chiral Naphthalimide Dyes

被引:47
作者
Li, Yang [1 ]
Yao, Kun [1 ]
Chen, Yihan [1 ]
Quan, Yiwu [1 ]
Cheng, Yixiang [2 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab High Performance Polymer Mat & Technol, Nanjing 210023, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Adv Organ Mat, Nanjing 210023, Peoples R China
基金
中国国家自然科学基金;
关键词
circularly polarized luminescence; full-color emission; intramolecular hydrogen bond; naphthalimide derivatives; white emission; INTRAMOLECULAR CHARGE-TRANSFER; AGGREGATION-INDUCED EMISSION; FLUORESCENCE;
D O I
10.1002/adom.202100961
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Chiral emissive nematic liquid crystals (N*-LCs) can greatly amplify the circularly polarized luminescence (CPL) signals promoted by a highly regular spiral self-assembly in the LCs system. Naphthalimide (NI) derivatives have been assigned to be one of the most excellent chromophores for fluorescent materials. In this paper, a novel strategy is first developed to regulate full-color CPL behavior of N*-LCs through different chiral NI-based dyes. Chiral NI-based dyes are doped into nematic liquid crystals (E7, N-LCs) to form N*-LCs as CPL-active liquid crystal materials. Most interestingly, this kind of N*-LCs could emit standard white CPL signals (CIE coordinates: (0.31, 0.33)) by choosing the blue-red match of two chiral NI-based dyes at the appropriate ratio.
引用
收藏
页数:6
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