The first trans-configured cyclopalladated amine

被引：17

作者：

Calmuschi-Cula, B ^{[1
]}

Kalf, I ^{[1
]}

Wang, RM ^{[1
]}

Englert, U ^{[1
]}

机构：

[1] RWTH Aach Univ, Inst Inorgan Chem, D-52074 Aachen, Germany

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 22期

关键词：

D O I：

10.1021/om050524d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

More than 100 ortho-palladated neutral arylamines with two additional monodentate ligands, namely, a N- or P-bonded Lewis base L and a mononegative ligand X, correspond to the cis configuration with respect to their Pd-C and Pd-L bonds. In contrast, (S)-[2-(1-aminoethyl)phenyl-k(2)C(1),N]chloro(3,4,5-trichloropyridine-kN)palladium(II) represents the first structurally characterized trans-configured complex of this class.

引用

页码：5491 / 5493

页数：3

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