Specificity of the reaction of tetranitromethane with alkenes in nitromethane

被引:4
|
作者
Ivanova, O. A. [1 ]
Averina, E. B. [1 ]
Budynina, E. M. [1 ]
Korlyukov, A. A. [1 ]
Antipin, M. Yu. [1 ]
Kuznetsova, T. S. [1 ]
Zefirov, N. S. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
基金
俄罗斯基础研究基金会;
关键词
Alcohol; Organic Chemistry; Alkene; Nitromethane; Tetranitromethane;
D O I
10.1007/s11178-005-0333-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactions of tetranitromethane with a number of di- and trisubstituted olefins in nitromethane were studied. Vinylcyclopropanes and phenylcycloalkenes reacted with tetranitromethane in an unexpected fashion, leading to formation of alkyltrinitromethanes and vicinal nitro alcohols.
引用
收藏
页码:1265 / 1270
页数:6
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