Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems

被引：65

作者：

Islam, Rafique Ul ^{[1
]}

Witcomb, Michael J. ^{[2
]}

Scurrell, Michael S. ^{[3
]}

van der Lingen, Elma ^{[4
]}

Van Otterlo, Willem ^{[3
]}

Mallick, Kaushik ^{[4
]}

机构：

[1] Birla Inst Technol, Dept Appl Chem, Ranchi 835215, Bihar, India

[2] Univ Witwatersrand, Microscopy & Microanal Unit, ZA-2050 Johannesburg, South Africa

[3] Univ Witwatersrand, Sch Chem, Inst Mol Sci, ZA-2050 Johannesburg, South Africa

[4] MINTEK, Adv Mat Div, ZA-2125 Randburg, South Africa

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 02期

关键词：

POTASSIUM ARYL; NANOCOMPOSITES; POLYANILINE; REDUCTION; PARTICLES; OXIDATION; PLATINUM; HALIDES; METAL; ACIDS;

D O I：

10.1039/c0cy00071j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple and efficient procedure for Suzuki coupling of aryl bromides with phenylboronic acid, catalyzed by an in situ-generated palladium(0)-polymer composite in the absence of any phosphine ligand, has been reported. The catalyst is remarkably active having a high TOF value for both aryl and heteroaryl systems, and is recyclable up to three runs with minimum loss of efficiency.

引用

页码：308 / 315

页数：8

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