Synthesis, crystal structure, and gas adsorption property of microporous solid by assembly of 1-D coordination polymer with a zigzag skeleton

被引:11
作者
Takamizawa, S [1 ]
Nakata, E [1 ]
Saito, T [1 ]
机构
[1] Grad Sch Integrated Sci, Kanazawa Ku, Yokohama, Kanagawa 2360027, Japan
关键词
microporous solid; crystal structure; gas adsorption; dinuclear Rh complex; one-dimensional polymer;
D O I
10.1016/j.inoche.2003.10.028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A crystalline solid, [Rh(II)(2)(bza)(4)(1,5-nptd)](n) (bza and 1,5-nptd = benzoate and 1,5-naphthyridine), was synthesized and characterized by single-crystal X-ray diffraction analysis; the microporous compound demonstrates gas adsorbency with a N-2 BET surface area of 291.6 m(2) g(-1). (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:125 / 127
页数:3
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