One-pot Conversion from Lignocellulosic Biomass to Isosorbide

被引：13
作者：
Yamaguchi, Aritomo [1 ,2 ]
Mimura, Naoki [1 ]
Shirai, Masayuki [1 ,3 ]
Sato, Osamu [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Chem Proc Technol, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan
[2] Japan Sci & Technol Agcy JST, PRESTO, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan
[3] Iwate Univ, Fac Sci & Engn, Dept Chem & Biol Sci, 4-3-5 Ueda, Morioka, Iwate 0208551, Japan
来源：
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE | 2016年 / 59卷 / 04期
关键词：
Biomass conversion; Lignocellulose; Cellulose; Isosorbide; Sugar alcohol; Ruthenium catalyst; SUPPORTED METAL-CATALYSTS; TEMPERATURE LIQUID WATER; SUGAR ALCOHOLS; HETEROGENEOUS CATALYSTS; WOOD CHIPS; CELLULOSE; SORBITOL; DEHYDRATION; CHEMICALS; CARBON;
D O I：
10.1627/jpi.59.155
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Isosorbide and its derivatives are important monomers in the polymer industry and valuable intermediates in the pharmaceutical industry. Recently, one-pot conversion of cellulose into isosorbide has been reported using supported metal catalysts and acid catalysts. The present study investigated one-pot conversion of lignocellulosic biomass into isosorbide using supported metal catalyst and ion-exchange resin Amberlyst 70. Isosorbide could be obtained from one-pot conversion of Japanese cedar with 25.4 % yield using supported ruthenium catalyst and Amberlyst 70 at 463 K. Isosorbide yields from one-pot conversion of eucalyptus and bagasse were 8.3 % and 12.8 %, respectively. One-pot conversion has the potential to be a powerful method to convert lignocellulosic biomass to useful chemicals.
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收藏
页码：155 / 159
页数：5
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