One-pot Conversion from Lignocellulosic Biomass to Isosorbide

被引：13

作者：

Yamaguchi, Aritomo ^{[1
,2
]}

Mimura, Naoki ^{[1
]}

Shirai, Masayuki ^{[1
,3
]}

Sato, Osamu ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Chem Proc Technol, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan

[2] Japan Sci & Technol Agcy JST, PRESTO, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan

[3] Iwate Univ, Fac Sci & Engn, Dept Chem & Biol Sci, 4-3-5 Ueda, Morioka, Iwate 0208551, Japan

来源：

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE | 2016年 / 59卷 / 04期

关键词：

Biomass conversion; Lignocellulose; Cellulose; Isosorbide; Sugar alcohol; Ruthenium catalyst; SUPPORTED METAL-CATALYSTS; TEMPERATURE LIQUID WATER; SUGAR ALCOHOLS; HETEROGENEOUS CATALYSTS; WOOD CHIPS; CELLULOSE; SORBITOL; DEHYDRATION; CHEMICALS; CARBON;

D O I：

10.1627/jpi.59.155

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Isosorbide and its derivatives are important monomers in the polymer industry and valuable intermediates in the pharmaceutical industry. Recently, one-pot conversion of cellulose into isosorbide has been reported using supported metal catalysts and acid catalysts. The present study investigated one-pot conversion of lignocellulosic biomass into isosorbide using supported metal catalyst and ion-exchange resin Amberlyst 70. Isosorbide could be obtained from one-pot conversion of Japanese cedar with 25.4 % yield using supported ruthenium catalyst and Amberlyst 70 at 463 K. Isosorbide yields from one-pot conversion of eucalyptus and bagasse were 8.3 % and 12.8 %, respectively. One-pot conversion has the potential to be a powerful method to convert lignocellulosic biomass to useful chemicals.

引用

页码：155 / 159

页数：5

共 34 条

[1] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[2] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[3] Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water [J].

Cortright, RD ;

Davda, RR ;

Dumesic, JA .

NATURE, 2002, 418 (6901) :964-967

[4] Cracking of cellulose over supported metal catalysts [J].

Dhepe, Paresh L. ;

Fukuoka, Atsushi .

CATALYSIS SURVEYS FROM ASIA, 2007, 11 (04) :186-191

[5] Selective Transformation of Cellulose into Sorbitol by Using a Bifunctional Nickel Phosphide Catalyst [J].

Ding, Li-Ning ;

Wang, Ai-Qin ;

Zheng, Ming-Yuan ;

Zhang, Tao .

CHEMSUSCHEM, 2010, 3 (07) :818-821

[6] Promises in direct conversion of cellulose and lignocellulosic biomass to chemicals and fuels: Combined solvent-nanocatalysis approach for biorefinary [J].

Dutta, Saikat ;

Pal, Sharmistha .

BIOMASS & BIOENERGY, 2014, 62 :182-197

[7] ISOSORBIDE - PREPARATION, PROPERTIES AND CHEMISTRY [J].

FLECHE, G ;

HUCHETTE, M .

STARCH-STARKE, 1986, 38 (01) :26-30

[8] Catalytic conversion of cellulose into sugar alcohols [J].

Fukuoka, Atsushi ;

Dhepe, Paresh L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (31) :5161-5163

[9] Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid [J].

Geboers, Jan ;

Van de Vyver, Stijn ;

Carpentier, Kevin ;

Jacobs, Pierre ;

Sels, Bert .

CHEMICAL COMMUNICATIONS, 2011, 47 (19) :5590-5592

[10] HEXITOL ANHYDRIDES - THE STRUCTURE OF ISOSORBIDE, A CRYSTALLINE DIANHYDROSORBITOL [J].

HOCKETT, RC ;

FLETCHER, HG ;

SHEFFIELD, EL ;

GOEPP, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (06) :927-930

← 1 2 3 4 →