Influence of the Encapsulated Clusters on the Electrochemical Behaviour of Endohedral Fullerene Derivatives: Comparative Study of N-Tritylpyrrolidino Derivatives of Sc3N@Ih-C80 and Lu3N@Ih-C80

被引:16
作者
Chen, Ning [1 ]
Pinzon, Julio R. [2 ]
Echegoyen, Luis [1 ]
机构
[1] Univ Texas El Paso, El Paso, TX 79968 USA
[2] Clemson Univ, Clemson, SC 29634 USA
基金
美国国家科学基金会;
关键词
cluster compounds; electrochemistry; fullerenes; liquid chromatography; mass spectrometry; I-H SC3N-AT-C-80; METALLOFULLERENES; METAL; CLUSTERFULLERENES; SEPARATION; X=0-3; REACTIVITY; STATES; YIELD; ANION;
D O I
10.1002/cphc.201001015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Clutching the ball: A comparative electrochemical study of the N-tritylpyrrolidino derivatives of Sc3N@Ih-C80 (picture, left) and Lu3N@Ih-C80 (picture, right) shows a significant influence of the encapsulated clusters on the physical and electrochemical properties of endohedral fullerene derivatives. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1422 / 1425
页数:4
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