Influence of the Encapsulated Clusters on the Electrochemical Behaviour of Endohedral Fullerene Derivatives: Comparative Study of N-Tritylpyrrolidino Derivatives of Sc3N@Ih-C80 and Lu3N@Ih-C80

被引:16
作者
Chen, Ning [1 ]
Pinzon, Julio R. [2 ]
Echegoyen, Luis [1 ]
机构
[1] Univ Texas El Paso, El Paso, TX 79968 USA
[2] Clemson Univ, Clemson, SC 29634 USA
基金
美国国家科学基金会;
关键词
cluster compounds; electrochemistry; fullerenes; liquid chromatography; mass spectrometry; I-H SC3N-AT-C-80; METALLOFULLERENES; METAL; CLUSTERFULLERENES; SEPARATION; X=0-3; REACTIVITY; STATES; YIELD; ANION;
D O I
10.1002/cphc.201001015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Clutching the ball: A comparative electrochemical study of the N-tritylpyrrolidino derivatives of Sc3N@Ih-C80 (picture, left) and Lu3N@Ih-C80 (picture, right) shows a significant influence of the encapsulated clusters on the physical and electrochemical properties of endohedral fullerene derivatives. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1422 / 1425
页数:4
相关论文
共 28 条
[1]  
Akasaka T., 2002, Endofullerenes: A New Family of Carbon Clusters
[2]  
[Anonymous], NATURE
[3]   A pirouette on a metallofullerene sphere:: Interconversion of isomers of N-tritylpyrrolidino Ih Sc3N@C80 [J].
Cai, Ting ;
Slebodnick, Carla ;
Xu, Liaosa ;
Harich, Kim ;
Glass, Thomas E. ;
Chancellor, Christopher ;
Fettinger, James C. ;
Olmstead, Marilyn M. ;
Balch, Alan L. ;
Gibson, Harry W. ;
Dorn, Harry C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (19) :6486-6492
[4]   Unexpected chemical and electrochemical properties of M3N@C80 (M = Sc, Y, Er) [J].
Cardona, Claudia M. ;
Elliott, Bevan ;
Echegoyen, Luis .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (19) :6480-6485
[5]   Trimetallic nitride endohedral metallofullerenes: Reactivity dictated by the encapsulated metal cluster [J].
Cardona, CM ;
Kitaygorodskiy, A ;
Echegoyen, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (29) :10448-10453
[6]   Chemical, Electrochemical, and Structural Properties of Endohedral Metallofullerenes [J].
Chaur, Manuel N. ;
Melin, Frederic ;
Ortiz, Angy L. ;
Echegoyen, Luis .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) :7514-7538
[7]   Comparative spectroscopic and reactivity studies of Sc3-xYxN@C80 (x=0-3) [J].
Chen, Ning ;
Fan, Lou-Zhen ;
Tan, Kai ;
Wu, Yue-Qin ;
Shu, Chun-Ying ;
Lu, Xin ;
Wang, Chun-Ru .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (32) :11823-11828
[8]   Size effect of encaged clusters on the exohedral chemistry of endohedral fullerenes:: A case study on the pyrrolidino reaction of ScxGd3-xN@C80 (x=0-3) [J].
Chen, Ning ;
Zhang, Er-Yun ;
Tan, Kai ;
Wang, Chun-Ru ;
Lu, Xin .
ORGANIC LETTERS, 2007, 9 (10) :2011-2013
[9]   Endohedral clusterfullerenes - playing with cluster and cage sizes [J].
Dunsch, Lothar ;
Yang, Shangfeng .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (24) :3067-3081
[10]   Metal nitride cluster fullerenes: Their current state and future prospects [J].
Dunsch, Lothar ;
Yang, Shangfeng .
Small, 2007, 3 (08) :1298-1320