Hydrogen Solubilities in the IUPAC Ionic Liquid 1-Hexyl-3-methylimidazolium Bis(Trifluoromethylsulfonyl)Imide

被引：35

作者：

Raeissi, S. ^{[1
]}

Florusse, L. J. ^{[2
]}

Peters, C. J. ^{[3
,4
]}

机构：

[1] Shiraz Univ, Sch Chem & Petr Engn, Shiraz 71345, Iran

[2] Delft Univ Technol, Dept Chem Technol, Fac Sci & Technol, NL-2628 BL Delft, Netherlands

[3] Delft Univ Technol, Lab Proc Equipment, Dept Proc & Energy, Fac Mech Maritime & Mat Engn, NL-2628 CA Delft, Netherlands

[4] Petr Inst, Dept Chem Engn, Abu Dhabi, U Arab Emirates

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 04期

关键词：

CARBON-DIOXIDE; H-2; ETHANE; SALTS; CO2;

D O I：

10.1021/je101060k

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Because of some disagreements among published data on the solubilities of gases in ionic liquids, an IUPAC project to establish recommended values for some properties and suggest suitable measurement methods was initiated. As part of this large project, this study focused on the solubility of hydrogen gas in the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. High-pressure gas solubilities were measured at various temperatures up to 370 K and pressures up to 12 MPa. The results showed very good agreement between the data measured in this laboratory and those of two other laboratories where the hydrogen solubilities in the same IUPAC sample were measured using differing experimental setups.

引用

收藏

页码：1105 / 1107

页数：3

相关论文

共 17 条

[1] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[2] High-pressure phase behavior of ethane with 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [J].

Florusse, Louw J. ;

Raeissi, Sona ;

Peters, Cor J. .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (06) :1283-1285

[3] Low-pressure solubility and thermodynamics of solvation of carbon dioxide, ethane, and hydrogen in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide between temperatures of 283 K and 343 K [J].

Gomes, M. F. Costa .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (02) :472-475

[4] THE INTERFACIAL STABILITY OF LI WITH 2 NEW SOLVENT-FREE IONIC LIQUIDS - 1,2-DIMETHYL-3-PROPYLIMIDAZOLIUM IMIDE AND METHIDE [J].

KOCH, VR ;

NANJUNDIAH, C ;

APPETECCHI, GB ;

SCROSATI, B .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (07) :L116-L118

[5] Solubility of H2 in the ionic liquid [bmim][PF6] [J].

Kumelan, J ;

Kamps, APS ;

Tuma, D ;

Maurer, G .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (01) :11-14

[6] Solubility of the single gases methane and xenon in the ionic liquid [hmim] [Tf2N] [J].

Kumelan, Jacek ;

Kamps, Alvaro Perez-Salado ;

Tuma, Dirk ;

Maurer, Gerd .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (24) :8236-8240

[7] Solubility of the single gases H2 and CO in the ionic liquid [bmim] [CH3SO4] [J].

Kumelan, Jacek ;

Kamps, Alvaro Perez-Salado ;

Tuma, Dirk ;

Maurer, Gerd .

FLUID PHASE EQUILIBRIA, 2007, 260 (01) :3-8

[8] Solubility of CO2 in the ionic liquid [hmim][Tf2N] [J].

Kumelan, Jacek ;

Kamps, Ivaro Perez-Salado ;

Tuma, Dirk ;

Maurer, Gerd .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (11) :1396-1401

[9] Solubility of H2 in the ionic liquid [hmim][Tf2N] [J].

Kumelan, Jacek ;

Kamps, Alvaro Perez-Salado ;

Tuma, Dirk ;

Maurer, Gerd .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (04) :1364-1367

[10] Improving carbon dioxide solubility in ionic liquids [J].

Muldoon, Mark J. ;

Aki, Sudhir N. V. K. ;

Anderson, Jessica L. ;

Dixon, JaNeille K. ;

Brennecke, Joan F. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (30) :9001-9009