Electrocatalytic hydrogen evolution using triaryl corrole cobalt complex

被引：24

作者：

Lin, Huan ^{[1
]}

Hossain, Md Sahadat ^{[1
]}

Zhan, Shu-Zhong ^{[1
]}

Liu, Hai-Yang ^{[1
]}

Si, Li-Ping ^{[2
]}

机构：

[1] South China Univ Technol, Dept Chem, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510640, Peoples R China

[2] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528000, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2020年 / 34卷 / 05期

基金：

中国国家自然科学基金;

关键词：

cobalt; corrole; electrocatalysis; hydrogen evolution; 1ST DIRECT SYNTHESIS; OXYGEN REDUCTION; WATER OXIDATION; ACETIC-ACID; CARBON; REACTIVITY; CATALYSTS; ELECTRODE; IRON;

D O I：

10.1002/aoc.5583

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three cobalt triaryl corroles bearing an electron-withdrawing or electron-donating group at 10-meso-phenyl were synthesized and characterized. Two of them are new cobalt corroles prepared in this study. These cobalt corroles were characterized using high-resolution mass spectrometry, UV-Vis., nuclear magnetic resonance, X-ray photoelectron spectroscopy, and single-crystal X-ray structure determination. All synthesized cobalt corroles efficiently catalyzed the hydrogen evolution reaction (HER) in neutral aqueous media at an overpotential of 838 mV. The HER activity of these cobalt corroles significantly depended on the virtue of peripheral substituents.

引用

页数：10

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