Degradation products of aliphatic and aliphatic-aromatic polyesters

被引:45
|
作者
Hakkarainen, Minna [1 ]
Albertsson, Ann-Christine [1 ]
机构
[1] Royal Inst Technol KTH, Sch Chem Sci & Engn, Dept Fibre & Polymer Technol, SE-10044 Stockholm, Sweden
关键词
chromatography; degradation product; degradation; environmental impact; polyester;
D O I
10.1007/12_2007_128
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Analysis of degradation products needs to be included in degradability testing to ensure the environmental adaptability of degradable polymers. Identification of breakdown products from environmental degradation is important for understanding the degradation process, environmental interaction and impact of degradable polymers. with regard to degradability aliphatic polyesters are a particularly interesting group of polymers. They are susceptible to hydrolysis and biological attack due to the ester groups in the main chain. This paper summarizes the work done on the chromatographic analysis of degradation products from the most common aliphatic and aliphatic-aromatic polyesters under different abiotic and biotic conditions including simulated, accelerated and real environmental conditions.
引用
收藏
页码:85 / 116
页数:32
相关论文
共 50 条
  • [11] Degradation of aliphatic and aliphatic-aromatic co-polyesters by depolymerases from Roseateles depolymerans strain TB-87 and analysis of degradation products by LC-MS
    Shah, Aamer Ali
    Eguchi, Tomoaki
    Mayumi, Daisuke
    Kato, Satoshi
    Shintani, Noboru
    Kamini, Numbi Ramudu
    Nakajima-Kambe, Toshiaki
    POLYMER DEGRADATION AND STABILITY, 2013, 98 (12) : 2722 - 2729
  • [12] Photochemical transformation of aliphatic-aromatic polyesters and its impacts to degradability
    Maurer-Jones, Melissa
    Zumstein, Michael
    Sander, Michael
    Mc Neill, Kristopher
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [13] Synthesis and characterization of aliphatic-aromatic hyperbranched polyesters with high organosolubility
    Haroon A. M. Saeed
    Yassir A. Eltahir
    Yumin Xia
    Yimin Wang
    Russian Journal of Applied Chemistry, 2014, 87 : 1481 - 1488
  • [14] Aliphatic polyesters: Abiotic and biotic degradation and degradation products
    Hakkarainen, M
    DEGRADABLE ALIPHATIC POLYESTERS, 2002, 157 : 113 - 138
  • [15] Atmospheric and soil degradation of aliphatic-aromatic polyester films
    Kijchavengkul, Thitisilp
    Auras, Rafael
    Rubino, Maria
    Alvarado, Edgar
    Camacho Montero, Jose Roberto
    Rosales, Jorge Mario
    POLYMER DEGRADATION AND STABILITY, 2010, 95 (02) : 99 - 107
  • [16] Effect of aliphatic segment length and content on crystallization and biodegradation properties of aliphatic-aromatic co-polyesters
    Chen, Meng
    Cai, Chunhua
    Bao, Jie
    Du, Yuliu
    Gao, Hongbing
    Liu, Xiucai
    POLYMER DEGRADATION AND STABILITY, 2022, 203
  • [17] SANS Investigation of Global and Segmental Structures of Hyperbranched Aliphatic-Aromatic Polyesters
    Burchard, W.
    Khalyavina, A.
    Lindner, P.
    Schweins, R.
    Friedel, P.
    Wiemann, M.
    Lederer, A.
    MACROMOLECULES, 2012, 45 (07) : 3177 - 3187
  • [18] CHLOROMETHYLATION OF ALIPHATIC-AROMATIC KETONES
    ODOEVA, GA
    EPSHTEIN, GL
    SOCHILIN, EG
    ZHURNAL ORGANICHESKOI KHIMII, 1970, 6 (03): : 478 - &
  • [19] REGULAR ALIPHATIC-AROMATIC POLYOXAMIDES
    STEVENSO.D
    GAUDIANA, RA
    VOGL, O
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1974, : 80 - 80
  • [20] An Easy Strategy for the Synthesis of Well-Defined Aliphatic-Aromatic Hyperbranched Polyesters
    Schallausky, F.
    Erber, M.
    Komber, H.
    Lederer, A.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (22) : 2331 - 2338