Enhanced solar-light-driven photocatalytic performance by the synergistic effects of F- doped and Ag loaded SrTiO3 cubic nanoparticles

被引:11
作者
Yu, Yaru [1 ]
Lu, Zunming [1 ]
Guo, Qiang [1 ]
Yu, Jingjing [1 ]
Li, Yingxin [1 ]
Zhang, Xinghua [1 ]
Cheng, Yahui [2 ,3 ]
Yao, Yingwu [4 ]
Liu, Hui [5 ]
机构
[1] Hebei Univ Technol, Sch Mat Sci & Engn, Tianjin 300130, Peoples R China
[2] Nankai Univ, Dept Elect, Tianjin 300350, Peoples R China
[3] Nankai Univ, Key Lab Photo Elect Thin Film Devices & Technol T, Tianjin 300350, Peoples R China
[4] Hebei Univ Technol, Sch Chem, Tianjin 300130, Peoples R China
[5] Tianjin Univ, Inst New Energy Mat, Res Grp Quantum Dot Mat & Devices, Tianjin 300350, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalytic; F- doped SrTiO3; Ag loaded SrTiO3; Synergistic effect; TIO2 NANOTUBE ARRAYS; VISIBLE-LIGHT; REDUCTION; CO2; AU; NANOCOMPOSITES; EVOLUTION; ENERGY; RH;
D O I
10.1016/j.cplett.2017.12.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ag-SrTiFxO1-x nanocomposites (Ag-STFO) were prepared via one-pot solvothermal method and exhibited outstanding photocatalytic performance for degrading the Rhodamine B (RHB). Especially, 0.5 wt% Ag-STFO showed the best degradation rate of 95.7% under simulated solar light irradiation for 3 h. It was found that efficient photocatalytic efficiency is mainly attributed to the synergistic effect of Ag nanoparticles and F ions. Especially, the presence of F ions not only changed the band structure but also changed the morphology (exposed more high-energy crystal face) for SrTiO3. Moreover, the synergistic effect could effectively suppress the recombination of photo-generated electron/hole pairs for substantively enhancing the photocatalytic performance. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:94 / 101
页数:8
相关论文
共 36 条
[1]   A new strategy for energy innovation [J].
Alic, John ;
Sarewitz, Daniel ;
Weiss, Charles ;
Bonvillian, William .
NATURE, 2010, 466 (7304) :316-317
[2]   Synthesis of Cr-doped SrTiO3 photocatalyst and its application in visible-light-driven transformation of CO2 into CH4 [J].
Bi, Yiqing ;
Ehsan, Muhammad Fahad ;
Huang, Yan ;
Jin, Jiarui ;
He, Tao .
JOURNAL OF CO2 UTILIZATION, 2015, 12 :43-48
[3]   Selective dual-purpose photocatalysis for simultaneous H2 evolution and mineralization of organic compounds enabled by a Cr2O3 barrier layer coated on Rh/SrTiO3 [J].
Cho, Young-Jin ;
Moon, Gun-hee ;
Kanazawa, Tomoki ;
Maeda, Kazuhiko ;
Choi, Wonyong .
CHEMICAL COMMUNICATIONS, 2016, 52 (62) :9636-9639
[4]   Ligand-Exchange Assisted Formation of Au/TiO2 Schottky Contact for Visible-Light Photocatalysis [J].
Ding, Dawei ;
Liu, Kai ;
He, Shengnan ;
Gao, Chuanbo ;
Yin, Yadong .
NANO LETTERS, 2014, 14 (11) :6731-6736
[5]   Trends in non-metal doping of the SrTiO3 surface: a hybrid density functional study [J].
Guo, Yating ;
Qiu, Xiaowei ;
Dong, Hao ;
Zhou, Xin .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (33) :21611-21621
[6]   Progress in graphene-based photoactive nanocomposites as a promising class of photocatalyst [J].
Han, Lei ;
Wang, Ping ;
Dong, Shaojun .
NANOSCALE, 2012, 4 (19) :5814-5825
[7]   High-efficiency conversion of CO2 to fuel over ZnO/g-C3N4 photocatalyst [J].
He, Yiming ;
Wang, Yan ;
Zhang, Lihong ;
Teng, Botao ;
Fan, Maohong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 168 :1-8
[8]   Ag Nanoparticle Embedded TiO2 Composite Nanorod Arrays Fabricated by Oblique Angle Deposition: Toward Plasmonic Photocatalysis [J].
He, Yizhuo ;
Basnet, Pradip ;
Murph, Simona E. Hunyadi ;
Zhao, Yiping .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (22) :11818-11827
[9]   Photocatalyfic reduction of Cr(VI) in the presence of NO3- and Cl- electrolytes as influenced by Fe(III) [J].
Hsu, Chia-Lian ;
Wang, Shan-Li ;
Tzou, Yu-Min .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (22) :7907-7914
[10]   Rh-Doped SrTiO3 Photocatalyst Electrode Showing Cathodic Photocurrent for Water Splitting under Visible-Light Irradiation [J].
Iwashina, Katsuya ;
Kudo, Akihiko .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (34) :13272-13275