Synthesis of homochiral addition polymers derived from N-trityl-(S)-serine

被引：18

作者：

Bush, SM ^{[1
]}

North, M ^{[1
]}

机构：

[1] UNIV WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

POLYMER | 1996年 / 37卷 / 20期

关键词：

aminoacid; serine; acrylate;

D O I：

10.1016/0032-3861(96)00346-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical induced homo- and copolymerization (with methyl methacrylate) of methyl N-trityl-O-acryloyl-(S)-serine and methyl N-trityl-O-methacryloyl-(S)-serine to give optically active polymers is reported. The resulting polymers are optically active, but show a nonlinear dependence of specific rotation vs. incorporation of chiral monomer. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：4649 / 4652

页数：4

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