A dinuclear copper complex:: bis(μ-4-aminobenzoato) bis[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-aminobenzoic acid) dihydrate

被引:2
作者
Huang, Miao-Ling [1 ]
Xie, Qing-Fan [1 ]
Xian, Jing-Chun [1 ]
Chen, Yan-Min [1 ]
Zhou, Zi-Qiao [1 ]
机构
[1] Quanzhou Normal Univ, Dept Chem & Life Sci, Fujian 362000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808023647
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Cu-2(C7H6NO2)(2)(C12H8N2)(2)(H2O)(2)]center dot 2C(7)H(7)NO(2)center dot 2H(2)O, consists of a dinuclear [Cu-2(C7H6NO2)(2)(C12H8N2)(2)(H2O)(2)](2+) cation, two Cl-anions, two 4-aminobenzoic acid molecules and two disordered water molecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the 1,10-phenanthroline ligand and two O atoms of the two 4-aminobenzoic acid ligands and one water O atom. The Cu center dot center dot center dot Cu separation is 3.109 (2) angstrom. A twofold axis passes through the mid-point of the Cu center dot center dot center dot Cu vector.
引用
收藏
页码:M1086 / U1028
页数:13
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