Dichloro[cyclopropyl(2-pyridylmethylene)amino]copper(II)

被引：5

作者：

Miao, JY ^{[1
]}

机构：

[1] Baoji Coll Arts & Sci, Dept Chem & Chem Engn, Baoji 721007, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805028473

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [CuCl2(C9H10N2)], is a mononuclear copper(II) complex. The Cu-II ion is coordinated by two N atoms of the Schiff base ligand and by two terminal Cl anions in a distorted tetrahedral geometry. In the crystal structure, the molecules are linked through intermolecular C - H (...) Cl hydrogen bonds, forming chains running along the b axis.

引用

页码：M1981 / M1983

页数：3

共 16 条

[1] Copper(II) nitrite complexes of tripodal ligands derived from 1,1,1-tris(2-pyridyl)methylamine [J].

Arnold, PJ ;

Davies, SC ;

Durrant, MC ;

Griffiths, DV ;

Hughes, DL ;

Sharpe, PC .

INORGANICA CHIMICA ACTA, 2003, 348 :143-149

[2]

Bruker, 1998, SMART VERS 5 628 SAI

[3] A novel series of heterotrinuclear complexes involving imidazolate bridging Schiff's base ligands. Synthesis, crystal structure, and magnetic properties [J].

Colacio, E ;

Dominguez-Vera, JM ;

Ghazi, M ;

Kivekas, R ;

Klinga, M ;

Moreno, JM .

INORGANIC CHEMISTRY, 1998, 37 (12) :3040-3045

[4] Metal complexes of bibracchial Schiff base macrocycles [J].

Collinson, SR ;

Fenton, DE .

COORDINATION CHEMISTRY REVIEWS, 1996, 148 :19-40

[5] Crystal structure of the copper(II) ternary complex of N-salicylidene-L-serinato with 2,6-diaminopyridine.: Toxicity studies against Drosophila melanogaster [J].

García-Raso, A ;

Fiol, JJ ;

López-Zafra, A ;

Castro, JA ;

Cabrero, A ;

Mata, I ;

Molins, E .

POLYHEDRON, 2003, 22 (03) :403-409

[6] The preparation, characterization, crystal structure and biological activities of some copper(II) complexes of the 2-benzoylpyridine Schiff bases of S-methyl- and S-benzyldithiocarbazate [J].

Hossain, ME ;

Alam, MN ;

Begum, J ;

Ali, MA ;

Nazimuddin, M ;

Smith, FE ;

Hynes, RC .

INORGANICA CHIMICA ACTA, 1996, 249 (02) :207-213

[7] Synthesis, crystal structure and redox properties of bis-imidazolyl-containing copper(II) complexes [J].

Musie, GT ;

Li, XB ;

Powell, DR .

INORGANICA CHIMICA ACTA, 2003, 348 :69-74

[8] Copper(II) mediated anion dependent formation of Schiff base complexes [J].

Pal, S ;

Barik, AK ;

Gupta, S ;

Hazra, A ;

Kar, SK ;

Peng, SM ;

Lee, GH ;

Butcher, RJ ;

El Fallah, MS ;

Ribas, J .

INORGANIC CHEMISTRY, 2005, 44 (11) :3880-3889

[9] Ni(II) and Cu(II) Schiff base complexes with an extended H-bond network [J].

Raptopoulou, CP ;

Papadopoulos, AN ;

Malamatari, DA ;

Ioannidis, E ;

Moisidis, G ;

Terzis, A ;

Kessissoglou, DP .

INORGANICA CHIMICA ACTA, 1998, 272 (1-2) :283-290

[10] Synthesis, characterisation and X-ray crystal structure of copper(II) complexes with unsymmetrical tetradentate Schiff base ligands: first evidence of Cu(II) catalysed rearrangement of unsymmetrical to symmetrical complex [J].

Ray, MS ;

Bhattacharya, R ;

Chaudhuri, S ;

Righi, L ;

Bocelli, G ;

Mukhopadhyay, G ;

Ghosh, A .

POLYHEDRON, 2003, 22 (04) :617-624

← 1 2 →