Synthesis of Poly(Vinyl Alcohol-Graft-Hyperbranched Glycerol)

被引：2

作者：

King, Peter A. ^{[1
]}

Khosravi, Ezat ^{[1
]}

Musa, Osama M. ^{[2
]}

机构：

[1] Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England

[2] Ashland Specialty Ingredients, 1005 Route 202-206, Bridgewater, NJ 08807 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2017年 / 55卷 / 18期

关键词：

functionalization of polymers; graft copolymers; hyperbranched; poly(vinyl alcohol); ring-opening polymerization; POLYMERS; POLYGLYCEROL; COPOLYMERS; ACRYLATE);

D O I：

10.1002/pola.28582

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the first example of grafting hyperbranched polyglycerol onto poly(vinyl alcohol) via ring-opening polymerisation of glycidol to prepare poly(vinyl alcohol-graft-hyperbranched glycerol) (P[(VA)-g-(hPG)]). The effects of catalyst, molecular weight of PVA, reaction temperature, water content, moles of reagent, and addition time of reagent were also investigated. P[(VA)-g-(hPG)] with various mole fractions of hPG were prepared and the degrees of substitution and branching were determined. P[(VA)-g-(hPG)] displayed decreased degree of crystallinity and also increased solubility in water, compared to PVA. P[(VA)-g-(hPG)] is shown to be a superior hair styling polymer with a curl retention value of 85% after 4 h. (C) 2017 Wiley Periodicals, Inc.

引用

页码：3041 / 3047

页数：7

共 50 条

[1] SYNTHESIS OF POLY(VINYL ALCOHOL)-GRAFT-POLYSTYRENE
TEZUKA, Y
ARAKI, A
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1993, 194 (10): : 2827 - 2837
[2] Synthesis of Poly(vinyl alcohol)-graft-poly(ε-caprolactone) and poly(vinyl alcohol)-graft-poly(lactide)in Melt with Magnesium Hydride as Catalyst
Guerrouani, Nadia
Mas, Andre
Schue, Francois
JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (02) : 1188 - 1197
[3] Synthesis and characterization of novel photoactive polymer poly(vinyl alcohol)-graft-poly(vinyl naphthalene)
Rymarczyk-Machal, M
Zapotoczny, S
Nowakowska, M
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (08) : 2675 - 2683
[4] Poly(vinyl alcohol)/poly(glycerol) dendrimer hydrogel mediated green synthesis of silver nanoparticles
Marcondes, Pollyana
Rosas, Gisela Helou
Leyva Gonzalez, Maria Elena
Alencar de Queiroz, Alvaro Antonio
Marques, Paulo Sergio
POLIMEROS-CIENCIA E TECNOLOGIA, 2022, 32 (03):
[5] Synthesis of poly(vinyl acetate) - Chitin graft copolymers as a base for chitosan poly(vinyl alcohol) ion exchangers
Abdel-Mohdy, FA
Waly, A
Ibrahim, MS
Hebeish, A
POLYMERS & POLYMER COMPOSITES, 1998, 6 (03): : 147 - 154
[6] Synthesis of Poly(vinyl alcohol) Graft Copolymers by Living Cationic Polymerization in the Presence of Added Bases I. Design and Synthesis of Poly(vinyl alcohol) Graft Copolymers with Well-Controlled Poly(vinyl ether) Grafts
Sadahito Aoshima
Masakuni Ikeda
Koji Nakayama
Eiichi Kobayashi
Hiroyuki Ohgi
Toshiaki Sato
Polymer Journal, 2001, 33 : 610 - 616
[7] Synthesis of poly(vinyl alcohol) graft copolymers by living cationic polymerization in the presence of added bases I. Design and synthesis of poly(vinyl alcohol) graft copolymers with well-controlled poly(vinyl ether) grafts
Aoshima, S
Ikeda, M
Nakayama, K
Kobayashi, E
Ohgi, H
Sato, T
POLYMER JOURNAL, 2001, 33 (08) : 610 - 616
[8] Synthesis of hyperbranched poly(glycerol-diacid) oligomers
Wyatt, Victor T.
Nunez, Alberto
Foglia, Thomas A.
Marmer, William N.
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2006, 83 (12) : 1033 - 1039
[9] Synthesis, characterization and cytotoxicity of TMC-graft-poly(vinyl alcohol) copolymers
Martins, Alessandro F.
Bueno, Pedro V. A.
Follmann, Heveline D. M.
Nocchi, Samara R.
Nakamura, Celso V.
Rubira, Adley F.
Muniz, Edvani C.
CARBOHYDRATE RESEARCH, 2013, 381 : 153 - 160
[10] Synthesis and grafting efficiency of poly(vinyl alcohol)-graft-Fibroin peptides
Research Institute of Biological and Spinning Materials, Tianjin Polytechnic University, Tianjin-300160, China
Iran Polym J Eng Ed, 2009, 8 (663-670):

← 1 2 3 4 5 →