Colorimetric and fluorescent probe for real-time detection of palladium (II) ion in aqueous medium and live cell imaging

被引:25
作者
Chen, Xiangzhu [1 ]
Wang, Hongmei [1 ]
Ma, Xiaodong [1 ]
Wang, Mian [1 ]
Zhang, Yuanyuan [1 ]
Gao, Gui [1 ]
Liu, Jingjing [1 ]
Hou, Shicong [1 ]
机构
[1] China Agr Univ, Dept Chem, Beijing 100193, Peoples R China
关键词
Coumarin oxime; Sulfur atom; Palladium (II) ion; Aqueous solution; Fluorescence imaging; TURN-ON CHEMODOSIMETER; LIVING CELLS; SENSITIVE DETECTION; DUAL PROBE; PD2+; SPECTROMETRY; PLATINUM; EXPOSURE; RHODIUM; WATER;
D O I
10.1016/j.dyepig.2017.08.063
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel fluorescent and colorimetric sensor (WM-S) was synthesized from coumarin oxime and 2-chloroethyl methyl sulfide in a straightforward manner. The sensor displayed high selectivity for detection of Pd2+ over other metal ions (Cu2+ and Hg2+ in particular). The probe also exhibited high sensitivity for recognition of Pd2+ in aqueous media and can detect trace amounts of Pd2+ in real time, with a detection limit as low as 41.5 nM. Fluorescence imaging experiments of Pd2+ in HeLa cells indicated that the sensor can penetrate cell membranes and effectively detect intracellular Pd2+. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:286 / 291
页数:6
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