Concept for a single-shot mid-infrared spectrometer using synchrotron radiation

被引:11
作者
Schade, U. [1 ]
Ritter, E. [2 ]
Hegemann, P. [2 ]
Aziz, E. F. [1 ,3 ]
Hofmann, K. P. [4 ]
机构
[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, Methods Mat Dev, D-12489 Berlin, Germany
[2] Humboldt Univ, Expt Biophys, D-10115 Berlin, Germany
[3] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany
[4] Charite, Inst Med Phys & Biophys, D-10117 Berlin, Germany
基金
欧洲研究理事会;
关键词
Single-shot infrared spectroscopy; Fery prism spectrometer; Infrared synchrotron radiation; Focal plane array; PRISM; SPECTROSCOPY; SPECTRA; ULTRA;
D O I
10.1016/j.vibspec.2014.07.004
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Several attempts have been made to extend time-resolved mid infrared spectroscopy to higher time resolution. Such methods are either limited to specific samples that are cyclic and therefore allow the reaction under investigation to be repeated multiple times in the same manner, or they lack spectral resolution or sufficient signal-to noise ratio. Here, we report on a single-shot spectrometer concept which overcomes the aforementioned limitations utilizing fast linear detector arrays and highly brilliant infrared synchrotron radiation. The spectrometer may find applications, beside others, for the investigation of irreversible cascades of structural alterations in proteins. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:190 / 195
页数:6
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