Vaporization enthalpies of a series of the halogen-substituted fluorobenzenes

被引：14

作者：

Verevkin, Sergey P. ^{[1
,2
]}

Emel'yanenko, Vladimir N. ^{[2
]}

Varfolomeev, Mikhail A. ^{[2
]}

Solomonov, Boris N. ^{[2
]}

Zherikova, Kseniya V. ^{[3
]}

Melkhanova, Svetlana V. ^{[1
]}

机构：

[1] Univ Rostock, Dept Phys Chem, D-18059 Rostock, Germany

[2] Kazan Fed Univ, Dept Phys Chem, Kazan 420008, Russia

[3] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

FLUID PHASE EQUILIBRIA | 2015年 / 387卷

关键词：

Halogen substituted benzenes; Vapor pressure; Transpiration method; Enthalpy of vaporization; Correlation gas-chromatography; Group-additivity; VAPOR-PRESSURES;

D O I：

10.1016/j.fluid.2014.12.023

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor pressures of 2-, 3-, and 4-halogen-substituted fluorobenzenes (halogen = Cl, Br, and I) were measured by the transpiration method. Molar standard enthalpies of vaporization were calculated from temperature dependences of vapor pressures. New enthalpies of vaporization at 298 K and those available from literature were tested for consistency by correlation gas-chromatography and evaluated by group-additivity method. Contributions to vaporization due to mutual interactions of halogens on the benzene ring were derived and recommended for prediction vaporization enthalpies of halogen-substituted aromatics. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：160 / 168

页数：9

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