Synthesis of new α,α′,β-trisubstituted β-lactones as monomers for hydrolyzable polyesters

被引：17

作者：

Barbaud, C ^{[1
]}

Abdillah, F ^{[1
]}

Fabienne, F ^{[1
]}

Guerrouache, M ^{[1
]}

Guérin, P ^{[1
]}

机构：

[1] Univ Paris 12, CNRS, UMR C7581, Lab Rech Polymeres, F-94320 Thiais, France

来源：

DESIGNED MONOMERS AND POLYMERS | 2003年 / 6卷 / 04期

关键词：

alkylation; dialkylmalic acids; lactonization; 4-alkyloxycarbonyl-3,3-dialkyl-2-oxetanones; poly(benzyl (R,S)-3,3-dimethylmalate;

D O I：

10.1163/156855503771816822

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Novel alpha,alpha',beta-trisubstitute beta-lactones have been prepared by a concise and efficient synthesis in five steps from commercial racemic diethyl oxalpropionate. These lactones with different lateral groups can be polymerized or co-polymerized for obtaining polyesters with high molecular weight. Chemical modification of these functionalized hydrolyzable polymers will be used to adjust their properties to the selected temporary applications.

引用

页码：353 / 367

页数：15

共 25 条

[1] STEREOSPECIFIC INTRODUCTION OF DOUBLE-BONDS VIA THERMOLYSIS OF BETA-LACTONES [J].

ADAM, W ;

BAEZA, J ;

LIU, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (06) :2000-&

[2]

Anh N.T., 1976, TETRAHEDRON LETT, V17, P155

[3]

ANH NT, 1977, NOUV J CHIM, V1, P61

[4] CONVERSION OF SERINE TO STEREOCHEMICALLY PURE BETA-SUBSTITUTED ALPHA-AMINO-ACIDS VIA BETA-LACTONES [J].

ARNOLD, LD ;

KALANTAR, TH ;

VEDERAS, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) :7105-7109

[5] SYNTHESIS OF STEREOREGULAR POLY(ALKYL MALOLACTONATES) [J].

ARNOLD, SC ;

LENZ, RW .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1986, 6 :285-303

[6] PREPARATION OF CHIRAL SUBSTITUTED SUCCINIC ACIDS [J].

BAJWA, JS ;

MILLER, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (07) :1114-1116

[7] Poly(β-malic acid) derivatives with non-charged hydrophilic lateral groups:: synthesis and characterization [J].

Barbaud, C ;

Cammas-Marion, S ;

Guérin, P .

POLYMER BULLETIN, 1999, 43 (4-5) :297-304

[8]

BHAT KS, 1985, INDIAN J CHEM B, V24, P509

[9] A NOVEL SYNTHESIS OF OPTICALLY-ACTIVE 4-BENZYLOXYCARBONYL-2-OXETANONES AND 4-ALKYLOXYCARBONYL-2-OXETANONES [J].

CAMMAS, S ;

RENARD, I ;

BOUTAULT, K ;

GUERIN, P .

TETRAHEDRON-ASYMMETRY, 1993, 4 (08) :1925-1930

[10]

Cammas-Marion S, 2000, MACROMOL SYMP, V153, P167, DOI 10.1002/1521-3900(200003)153:1<167::AID-MASY167>3.0.CO

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