A schizophrenic water-soluble diblock copolymer

被引：10
|
作者：
Liu, SY [1 ]
Billingham, NC [1 ]
Armes, SP [1 ]
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 12期
关键词：
copolymerizations; micelles; polymerizations; polymers; self-assembly;
D O I：
10.1002/1521-3773(20010618)40:12<2328::AID-ANIE2328>3.0.CO;2-M
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two micellar states are possible for a novel PPO-PDEA diblock copolymer synthesized by atom-transfer radical polymerization. Subtle variation of the solution pH value and temperature is all that is needed to form both conventional micelles (with the PDEA block in the core) and reverse micelles (with the PPO block in the core) in aqueous media (shown schematically). DEA=2-(dietylamino)ethyl methacrylate, PO=propylene oxide.
引用
收藏
页码：2328 / +
页数：5
相关论文
共 50 条
  • [1] pH-responsive micelles and vesicles formed from a water-soluble schizophrenic diblock copolymer
    Enomoto, Ryusuke
    Khimani, Mehul
    Bahadur, Pratap
    Yusa, Shin-ichi
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (06) : 3117 - 3123
  • [2] Micelles and 'reverse micelles' with a novel water-soluble diblock copolymer
    Butun, Vural
    Sonmez, Sule
    Yarligan, Selma
    Taktak, Fadime Fulya
    Atay, Ahmet
    Butun, Sultan
    POLYMER, 2008, 49 (19) : 4057 - 4065
  • [3] Water-soluble complex formation of fullerene and thermo-responsive diblock copolymer
    Yano, Junki
    Ishihara, Kazuhiko
    Yusa, Shin-ichi
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2017, 55 (15) : 2432 - 2439
  • [4] Synthesis and characterization of a novel water-soluble cationic diblock copolymer with star conformation by ATRP
    Li, Shuzhao
    Xiao, Miaomiao
    Zheng, Anna
    Xiao, Huining
    MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2014, 43 : 350 - 358
  • [5] pH-Responsive Vesicles from a Schizophrenic Diblock Copolymer
    Du, Jianzhong
    O'Reilly, Rachel K.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (14) : 1530 - 1537
  • [6] A triple thermoresponsive schizophrenic diblock copolymer
    Zhang, Qilu
    Hong, Jong-Dal
    Hoogenboom, Richard
    POLYMER CHEMISTRY, 2013, 4 (16) : 4322 - 4325
  • [7] Polymeric surfactants for the new millennium: A pH-responsive, zwitterionic, schizophrenic diblock copolymer
    Liu, SY
    Armes, SP
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (08) : 1413 - 1416
  • [8] Monosaccharides as Versatile Units for Water-Soluble Supramolecular Polymers
    Leenders, Christianus M. A.
    Jansen, Gijs
    Frissen, Martijn M. M.
    Lafleur, Rene P. M.
    Voets, Ilja K.
    Palmans, Anja R. A.
    Meijer, E. W.
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (13) : 4608 - 4615
  • [9] A water-soluble antimicrobial acrylamide copolymer containing sulfitobetaine for enhanced oil recovery
    Gou, Shaohua
    He, Yang
    Ma, Yongtao
    Luo, Shan
    Zhang, Qin
    Jing, Dong
    Guo, Qipeng
    RSC ADVANCES, 2015, 5 (64) : 51549 - 51558
  • [10] RAFT Polymerization of an Intrinsically Stretchable Water-Soluble Block Copolymer Scaffold for PEDOT
    Kayser, Laure, V
    Russell, Madeleine D.
    Rodriquez, Daniel
    Abuhamdieh, Sami N.
    Dhong, Charles
    Khan, Salik
    Stein, Alexander N.
    Ramirez, Julian
    Lipomi, Darren J.
    CHEMISTRY OF MATERIALS, 2018, 30 (13) : 4459 - 4468
12345