Diorganotin(IV)benzoates: Structure, stability and equilibrium analysis by 1H and 119Sn NMR spectroscopy in acid solution

被引：1

作者：

Martinez Garcia, Juan Carlos ^{[1
]}

Montes Tolentino, Pedro ^{[1
]}

Hernandez Ahuactzi, Iran F. ^{[2
]}

Godoy Alcantar, Carolina ^{[1
]}

Ariza-Castolo, Armando ^{[3
]}

Guerrero Alvarez, Jorge Antonio ^{[1
]}

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Inst Invest Ciencias Basicas & Aplicadas, Av Univ 1001, Cuernavaca 62209, Morelos, Mexico

[2] Univ Guadalajara, Ctr Univ Tonala, Av Nuevo Periferico 555, Tonala 48525, Jalisco, Mexico

[3] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Av IPN 2508, San Pedro Zacatenco 07360, Mexico

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2020年 / 1209卷

关键词：

Four- and five-coordinate tin; Acid-base; Multinuclear magnetic resonance; Diorganotin(IV) carboxylates; Electrostatic potential; ORGANOTIN(IV) COMPLEXES; ANTITUMOR-ACTIVITY; IONIZATION; LIGANDS;

D O I：

10.1016/j.molstruc.2020.127915

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ten dibutyltin(IV) dicarboxylates were synthesized by a procedure based on a reactor and characterized by various structural elucidation techniques such as elemental analysis IR spectroscopy, FAB(+) and CI+ mass spectrometry, 1D and 2D(13)C and Sn-119 NMR experiments and TGA. A linear relationship between the sigma(Hammett) and Sn-119 NMR chemical shift was found due to the electron-withdrawing and electron-donating groups. H-1 and Sn-119 NMR titration experiments with DCI were carried in CD3OD solution to estimate the stability of the complexes and study the equilibrium between four- and five-coordinate complexes. The most basic sites for protonation were determined by analysis of the electrostatic potential by theoretical calculations. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：7

共 50 条

[1] Synthesis and spectroscopic [IR, NMR (1H, 13C, and 119Sn)] studies of organotin(IV) aryloxides
Mishra, S
Singh, A
MAIN GROUP METAL CHEMISTRY, 2003, 26 (04): : 221 - 227
[2] Phosphoramidic difluoride complexes of tin(IV) chloride:: A multinuclear (119Sn, 31P 19F and 1H) NMR characterisation in solution
Sanhoury, M. A. M. K.
Ben Dhia, M. T.
Essalah, K.
Khaddar, M. R.
POLYHEDRON, 2006, 25 (17) : 3299 - 3304
[3] Synthesis and spectroscopic (IR, 1H, 13C, and 119Sn NMR) characterization of mono- and diorganotin(IV) complexes containing sterically hindered N-arylsalicylaldiminate groups
Mishra, S
Goyal, M
Singh, A
MAIN GROUP METAL CHEMISTRY, 2002, 25 (07): : 437 - 444
[4] Synthesis and characterization by means of IR, 1H, 13C, 119Sn NMR and FAB-MS spectroscopy of some new organotin(IV) complexes
Dubey, R. K.
Singh, Avadhesh Pratap
Dwivedi, Nalini
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2011, 88 (06) : 845 - 851
[5] 119Sn Mossbauer, NMR (1H, 13C and 119Sn) and infrared study of tetracoordinated tin(IV) complexes with 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates
Baul, Tushar S. Basu
Das, Pradip
Rivarola, Eleonora
HYPERFINE INTERACTIONS, 2009, 194 (1-3): : 391 - 400
[6] The 1:1 and 2:1 complexes of diethyl ether with tin tetrachloride and their stability, studied by 119Sn NMR spectroscopy
Farcasiu, D
Leu, R
Ream, PJ
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, Royal Society of Chemistry (03): : 427 - 431
[7] 119Sn Mössbauer, NMR (1H, 13C and 119Sn) and infrared study of tetracoordinated tin(IV) complexes with 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates
Tushar S. Basu Baul
Pradip Das
Eleonora Rivarola
Hyperfine Interactions, 2009, 194 : 391 - 400
[8] DFT calculation of 1J(119Sn,13C) and 2J(119Sn,1H) coupling constants in di- and Trimethyltin(IV) compounds
Casella, Girolamo
Ferrante, Francesco
Saielli, Giacomo
INORGANIC CHEMISTRY, 2008, 47 (11) : 4796 - 4807
[9] 1H, 13C, 119Sn NMR, 119Sn Moessbauer, Infrared and Mass Spectrometric Studies of Organotin Carboxylates of 2-(2,3-Dimethylphenyl)aminobenzoic Acid and Their Effect on Microorganisms
Synth React Inorg Metal Org Chem, 6 (863):
[10] Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1H, 2H, 31P, and 119Sn MAS NMR
Bakhmutov, Vladimir I.
Elliott, Douglas W.
Contreras-Ramirez, Aida
Drake, Hannah
Zhou, Hong-Cai
INORGANIC CHEMISTRY, 2022, 61 (44) : 17759 - 17766

← 1 2 3 4 5 →