Preparation of microporous and mesoporous bimodel molecular sieves by heat treatment of ZSM-5

被引:0
|
作者
Wan, KS [1 ]
Liu, Q
Zhang, CM
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performace Ceram & Superfine M, Shanghai 200050, Peoples R China
[2] Tongji Univ, Dept Mat Sci & Engn, Shanghai 200092, Peoples R China
关键词
micro-meso bimodel molecular sieve; heat treatment; ZSM-5;
D O I
暂无
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A microporous and mesoporous bimodel molecular sieve was made from commercial ZSM-5 through heat treatment routine. The structure of the bimodel molecular sieve is strongly dependent on the treatment conditions (temperature and time). The sample treated at 1000degreesC for 2h has the highest mesopore phase, and the contribution of the mesopore phase to the BET surface area is comparable to the contribution of the micropore phase. The bimodel molecular sieve has narrow mesopore pore diameter distribution and high crystallinity.
引用
收藏
页码:1097 / 1101
页数:5
相关论文
共 8 条
  • [1] From microporous to mesoporous molecular sieve materials and their use in catalysis
    Corma, A
    [J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2373 - 2419
  • [2] Synthesis and characterization of composite molecular sieves comprising zeolite Beta with MCM-41 structures
    Guo, WP
    Xiong, CR
    Huang, LM
    Li, QZ
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (07) : 1886 - 1890
  • [3] Investigation of synthesizing MCM-41/ZSM-5 composites
    Huang, LM
    Guo, WP
    Deng, P
    Xue, ZY
    Li, QZ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (13): : 2817 - 2823
  • [4] Mesoporous zeolite single crystals
    Jacobsen, CJH
    Madsen, C
    Houzvicka, J
    Schmidt, I
    Carlsson, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) : 7116 - 7117
  • [5] Overgrowth of mesoporous MCM-41 on faujasite
    Kloetstra, KR
    Zandbergen, HW
    Jansen, JC
    vanBekkum, H
    [J]. MICROPOROUS MATERIALS, 1996, 6 (5-6): : 287 - 293
  • [6] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
    KRESGE, CT
    LEONOWICZ, ME
    ROTH, WJ
    VARTULI, JC
    BECK, JS
    [J]. NATURE, 1992, 359 (6397) : 710 - 712
  • [7] MESOPOROUS ALUMINOSILICATES PREPARED FROM ZEOLITES BY TREATMENT WITH AMMONIUM FLUOROSILICATE
    LEVANMAO, R
    LAVIGNE, JA
    SJIARIEL, B
    LANGFORD, CH
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (06) : 679 - 683
  • [8] Template-assisted self-assembly of macro-micro bifunctional porous materials
    Zhu, GS
    Qiu, SL
    Gao, FF
    Li, DS
    Li, YF
    Wang, RW
    Gao, B
    Li, BS
    Guo, YH
    Xu, RR
    Liu, Z
    Terasaki, O
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (06) : 1687 - 1693